Electroloysis Flashcards
SIMPLE electrolysis
*ALL molten electrolytes (no water to worry about)
Anion (-) goes to Anode (+)
Cation (+) goes to Cathode (-)
SIMPLE EG:
What happens to copper chloride in simple electrolysis, describe.
Chloride ions (-) go to Anode (+)
Copper ions (+) goes to Cathode (-)
At the Anode chlorine gas is realised (can see bubbling)
At the Cathode copper turns into an atom around electrode (can see orange substance)
CuCl2
CuSo4 ELECTROLYSIS
Using copper electrodes
In this the copper ions come off from the Anode replacing the ones taken by the Cathode.
It goes from atom to ion to atom.
CuSo4 EG:
What are the equations in this electrolysis, label.
Cathode/reduction:
Cu2++2e-> Cu (to atom)
Anode/oxidation:
Cu-2e->Cu2+ (to ion)
SOLUTION ELECTROLYSIS
Reactivity series
This is when the reactivity series comes into play.
Cathode - Attracts Cation and Hydrogen(H+)
Anode - Attracts Anion and Hydroxide(OH-)
At the Cathode, if the Cation is less reactive than Hydrogen the metal forms, otherwise Hydrogen forms. At the Anion Oxygen (see equations) always will form unless the Anion is Cl- / Br- / I-
SOLUTION EG:
What are the equations at the Anode and Cathode with CuSo4 in a solution with water.
Anode:
4OH- - 4e- > O2 + 2H2O
Cathode:
Cu2+ + 2e- > Cu