Constants + Chem equations Flashcards

1
Q

what is Avogadro’s number?

A

6.022 x 10^23

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2
Q

What is Planck’s constant?

A

6.6 × 10^-34 m2 kg / s

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3
Q

What is the formula for the energy of a photon?

A

E = hf

E = h x (c / λ)

h = planck’s constant = 6.6 x 10^-34

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4
Q

B- decay, what occurs?

A

convert a neutron to a proton + an electron.
This is the most common

atomic number –> go up by 1
mass number –> stay the same
neutron number –> down by 1

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5
Q

B+ decay, what occurs?

A

convert a proton to a neutron and a positron

atomic number –> down by 1
mass number –> stay the same
neutron number –> up by 1

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6
Q

electron capture, what occurs?

A

capture an electron and combine it with a proton to form a neutron.

atomic number –> down by 1
mass number –> stay the same
neutron number –> up by 1

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7
Q

formal charge calculation?

A

FC = valence - 1/2 bonding - lone

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8
Q

list the order of IMF strengths

A

ion-ion > ion-dipole > Hydrogen bonding > dipole-dipole > D-ID > ID-ID (dispersion forces)

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9
Q

t or f, radius increases to bottom left, acidity increases to bottom right.

A

true

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10
Q

equation for the heat of a phase change and the heat not during a phase change?

A

q = ΔH phase change x n

q = mcΔT

C = c x m

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11
Q

gibbs free energy?

A

ΔG = ΔH - TΔS

T in kelvin like always

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12
Q

What is STP?

A
T = 273 K 
P = 1atm = 760 mmHg = 760 Torr
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13
Q

Volume of an ideal gas at STP?

A

22.4 L

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14
Q

what is Boyle’s Law?

A

Isothermal law for gases

when temperature is constant, PV=nRT

Volume varies with 1 / P

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15
Q

What is Charle’s Law?

A

Isobaric law for gases

When pressure is constant, PV = nRT

Volume varies with T

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16
Q

ΔG° = ? for

a. when considering equilibrium reactions
b. when considering redox reactions?

A

ΔG° = -RTlnk

ΔG° = -nFE°

17
Q

what is Faradays constant?

A

96,500 Coulombs which is equal to the charge of 1 mole of electrons

18
Q

Nernst equation?

A

We can take

ΔG = ΔG° + RTlnQ and plug in ΔG° = -nFE°

ΔG = -nFE + RTlnQ
(note its E not E° since we are now dealing with ΔG)

solve for E to get

E = E° + (RT / nF) lnQ

OFTEN RT/F = 0.06

E = E° + (0.06 / n) lnQ

19
Q

elementary charge (e)?

A

1.6× 10-19 coulombs

20
Q

Coulombs constant (k)?

A

9 x 10^9 Nm^2 / C^2

21
Q

density of water?

A

1000 Kg / m^3

1g / cm^3

22
Q

speed of light?

A

3 x 10^8 m/s

23
Q

speed of sound?

A

340 m/s

24
Q

threshold of hearing?

A

Io = 10^-12 W/m^2

25
Q

gas constant?

A

0.08 L atm / mol K