7 Oxidation, reduction and redox reactions Flashcards

1
Q

what is oxidation

A

process of electron loss

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2
Q

what are oxidisaing agents

A

electron acceptors so they gain electrons

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3
Q

what is reduction

A

process of electron gain

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4
Q

what are reducing agents

A

electron donors so they lose electrons

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5
Q

what does OILRIG stand for

A
Oxidation
Is the
Loss of electrons
Reduction
Is the 
Gain of electrons
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6
Q

what does electron donors do

A

donate electrons

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7
Q

what do electron acceptors do

A

accept electrons

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8
Q

what is oxidation in terms of oxygen and hydrogen

A

addition of oxygen

loss of hydrogen

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9
Q

what is reduction in terms of oxygen and hydrogen

A

loss of oxygen

addition of hydrogen

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10
Q

what are spectator ions

A

ions that dont undergo any change to their oxidation number

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11
Q

what are the rules for assigning oxidation states

A

uncombined elements have oxidation state of 0
the sum of all oxidation states in a compound is 0 since all compounds are electrically nutreal
elements just bonded to identical atoms like O2 and H2 have oxidation state of 0
the oxidation state of a simple ion like Na+ is the same as its charge
in compound ions,the overall oxidation state is just the charge
hydrogen = +1 (except in metal hydrides eg.NaH where it is -1)
group 1 = always +1
group2 = always +2
group3 = 3+
group 5 = 3-
group6 = 2-
group7 = 1-
Aluminium = always +3
oxygen = -2 (except in peroxides where it is -1, and the compound OF2 where it is +2)
fluorine= always -1
chlorine= -1 (except with fluorine and oxygen where it has positive values)

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12
Q

what is an oxidation number

A

the charge on an atom if it were a simple ion

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13
Q

what is the oxidation state of N in NH3

A

hydrogen has an oxidation state of +1 ,make N your x
(x) +(+1 x 3)=0
x+3=0
x= -3

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14
Q

what is the oxidation state of Fe IN FeO

A

x +(-2)=0

x=2+

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15
Q

what is the oxidation state of V in V2O5

A

2x+(-10)=0
2x=10
x= 5+

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16
Q

what is the oxidation state of Fe in Fe2O3

A

2x+ (-6)=0
2x=6
x=3+

17
Q

what is the oxidation state of N in NH4+

A

x+(4)(+1)=+1
x+4=+1
x=-3

18
Q

what is the oxidation state of S in SO4 2-

A

x + (4)(-2)=-2

x=+6

19
Q

what is the oxidation state of P in PO4 3-

A

x + 4(2-)=-3

x=+5

20
Q

what is the oxidation state of N in NaNO3

A

1+x+(-6)=0
x+(-6)=-1
x=+5

21
Q

what are the rules for balancing half equations

A
  1. write down the species before and after a reaction
  2. balance any atoms apart from oxygen and hydrogen(these will be dealt with later)
  3. balance any oxygens with H20
  4. balance any hydrogens with H+ ions
  5. balance charges with electrons (e −)
22
Q

by balancing the half equations below combine them to produce an ionic equation
Fe2+ —> Fe3+
MnO4- —>Mn2+

A

Fe2+ —> Fe3+
Fe2+ —> Fe3+ + e −

MnO4- —> Mn2+
MnO4- —> Mn2+ + 4H2O
MnO4- +8H+ —>Mn2+ +4H20
5e − + MnO4- + 8H+ —> Mn2+ + 4H2O

(Fe2+ —> Fe3+ + e −) x5
5Fe2+ —-> 5Fe3+ + 5e −
5e − + MnO4- + 8H+ —> Mn2+ + 4H2O

the electrons cancel out and you get
5Fe2+ + MnO4- +8H+ —>Mn2+ +4H20 + 5Fe3+