Solutions CH9 Flashcards

1
Q

What is the electrostatic interaction between solute and solvent molecules?

A

Solvation (AKA Dissolution)

If water is involved, it is called Hydration

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2
Q

When new interactions are stronger than original ones, solvation is what (and is favored at what temperature)?

A

Exothermic; and favored at low temperatures

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3
Q

When new interactions are weaker than the original ones, solvation is what (and is favored at what temperature)?

A

Endothermic; and favored at high temperatures

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4
Q

When the overall enthalpy (H) change for dissolution is close to zero, it is called a(n)?

A

Ideal Solution

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5
Q

True/False: Both dilute and concentrated solutions are still considered unsaturated if the maximum equilibrium concentration (saturation) has not yet been reached?

A

True

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6
Q

What are two important rules for aqueous solutions?

A
  1. All salts of Group 1 metals (or cations) and NH4+ (ammonium) are water-soluble.
  2. All salts containing NO3- (nitrate) and acetate (CH3COO-) are water-soluble.
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7
Q

What refers to a molecule in which a certain cation is bonded to at least one electron pair donor (which could include the water molecule)?

A

Complex Ion (Coordination Compound)

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8
Q

What is the electron pair donor molecule in a complex ion called?

A

Ligand

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9
Q

Complex Ions are held together by what bond?

A

Coordinate Covalent Bonds (Lewis Acids and Bases)

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10
Q

The measure of the reactive capacity of a molecule (is equal to a mole of the species of interest -protons, hydroxide, ions, electrons, or ions).

A

Equivalent

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11
Q

Defined as the saturation point, where the solute concentration is at its maximum value for the given temperature and pressure.

A

Equilibrium

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12
Q

For a saturated solution of an ionic compound with the formula AmBn, the equilibrium constant for its solubility in aqueous solution is called?

A

Solubility Product Constant (Ksp)

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13
Q

We may not know whether the solution has reached saturation, and so to determine where the system is with respect to the equilibrium position, we can calculate a value called the?

A

Ion Product (IP)

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14
Q

The solubility of a salt is considerably reduced when it is dissolved in a solution that already contains one of its constituent ions as compared to its solubility in a pure solvent. This reduction in molar solubility is known as?

A

Common Ion Effect

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