Biochemistry intro 1 - atoms, biomolecules and reactions Flashcards

1
Q

Describe the basic structure of an atom

A

An atom has protons and neutrons in the nucleus and electrons orbiting around the nucleus in electron shells. A proton has a mass of 1 and a charge of +1, a neutron has a mass of 1 and no charge and an electron has a negligible mass and a charge of -1

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2
Q

What is ionisation energy?

A

The energy input needed to discharge an electron

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3
Q

What is a covalent bond and an ionic bond?

A

Covalent bond is shared pair of electrons whereas an ionic bond is the attraction of opposite charges

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4
Q

Does ionic radius increase or decrease as you move down a group?

A

As you move down a group, ionic radius increases due to more electron shells

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5
Q

What is bond energy?

A

The amount of energy required to break a bond (measured in kcal/mol)

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6
Q

What is van der waals interactions?

A

Interaction of electrons of non-polar substances

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7
Q

What is meant by electronegativity?

A

Electronegativity is the force than an atomic nucleus exerts on an electron (so how much they want an electron)

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8
Q

What is phosphorylation and de-phosphorylation?

A

Phosphorylation is the addition of a phosphate whereas de-phosphorylation is the removal of a phosphate

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9
Q

What is acylation and carboxylation?

A

Acylation is the addition of an acyl group (R-C=O) and carboxylation is the addition of a carboxyl group (COOH)

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10
Q

What is esterification?

A

When alcohol and acid react to form an ester

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11
Q

What is condensation and hydrolysis?

A

Condensation is the removal of water and hydrolysis is the addition of water

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12
Q

What is oxidation, reduction and a redox reaction?

A

Oxidation is the loss of electrons, reduction is the gain of electrons and a redox reaction is when one thing is being oxidised and the other thing is being reduced

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13
Q

What is meant by the terms reducing agent and oxidising agent?

A

A reducing agent is being oxidised so is an electron donor and an oxidising agent is being reduced so is an electron acceptor

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14
Q

Starting at an alkane, keep oxidising and name what you get until you reach carbon dioxide

A

Alkane → Alcohol → Aldehyde → Carboxylic acid → Carbon dioxide

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