:(((( Flashcards

1
Q

Esterification Reaction

A

An acid anhydride (or carboxylic acid) react with alcohols to form esters

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2
Q

Anhydride is

A

water removed from an acid

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3
Q

FeCl3 reacts with what to turn purple

A

phenol group

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4
Q

What makes salicylic acid unable to be consumed directly

A

-OH group (alcohol). Phenolic hydroxyl group

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5
Q

Acetic acid is a part of what food

A

vinegar

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6
Q

Ace-tyl-sali-cylic acid

A

Ace-tyl-sali-cylic acid

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7
Q

Spell the thing that is produced when salicylic acid and acetic anhydride combine

A

Ace-tyl-sali-cylic acid

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8
Q

Salicylic acid is a benzene ring with a

A

alcohol group and a carboxyl acid

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9
Q

Do NOT call -OH what

A

DO NOT call it hydroxide

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10
Q

Acetic anhydride is an ___ anhydride

A

acid anhydride

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11
Q

An alcohol group attached to a benzene ring is called

A

a phenol

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12
Q

Alcohol is a __ acid

A

Weak

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13
Q

A phenol is a ____ acid

A

Strong

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14
Q

All the negative side effects are linked to what

A

The hydroxyl group

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15
Q

The hydrogen from the alcohol group on salicylic acid attaches to what

A

The carbon on acetic anhydride

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16
Q

What are the products of this esterification reaction

A

Acetic acid and acetylsalicylic acid

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17
Q

The esterification reaction is jump started by what

A

An acid (H2So4)

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18
Q

Phenol group gets converted into

A

An ester

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19
Q

Why is it called acetylsalicylic acid and not just an ester

A

Because it still has a carboxylic acid

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20
Q

What is a lachrymator

A

A eye and nasal irritant

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21
Q

Concentrated sulfuric acid jump starts the reaction because

A

its a strong acid and a strong oxidizer

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22
Q

Concentrated sulfuric acid is a strong oxidizer and what

A

A strong acid

23
Q

The reason the aspirin creation has to happen in ice water is because

A

Cold lower solubility, allowing crystals to form

24
Q

What was the goal of the 3rd lab

A

To find the % of salicylic acid in commercial medication

25
ASA+NaOH creates
A form of ASA that does not have hydrogen
26
After creating the salicylic acid you add water to dilute it to
1 liter
27
To the stock solution you need to add H+ ions to reform the
salicylic acid
28
You add FeCl3-KCl-HCl in excess to the stock solution to add H+ ion that make
Salicylic acid
29
FeCl3 is added to stock so that
It can react with the phenol of the salicylic acid
30
KCL is added to
Maintain same ionic strength
31
HCl is added to
Add the H+ ion to make salicylic acid
32
What is added to the stock solution
FeCl3-KCl-Hcl
33
Analytical wavelength
Is where absorptance is the highest
34
What is Beer's Law
A=Ebc
35
In Beer's law (a=ebc) what is a
Absorptancy
36
In Beer's Law (a=ebc) what is e
Epsilon
37
In Beer's Law (A=ebc) what is b
The pathlength of light through the solution (the width of the cuvette)
38
In Beer's law (a=ebc) what is c
The concentraion
39
What is b typically
1cm
40
So, is b is always one that epsilon times b is just equal to epsilon. This is the ___
slope
41
The slope of concentration is what
Epsilon
42
Slope is found by
Rise/run
43
Beer's law (a=ebc) has NO
Y-intercept
44
If beer's law (a=ebc) has no y intercept then the equation starts
At the origin
45
Hydrolysis reaction is
A reaction of a substance with water
46
Why is Hcl added to the stock
To form salicylic acid
47
What is a hydrolysis reaction
A reaction of a substance with water
48
What is a reference (blank) solution
A solution containing all the components of the solution except the species being determined
49
What is an esterification reaction
Reaction of an alcohol with a carboxylic acid (or an acid anhydride) to form an ester
50
What is analytical wavelength
The place where absorptance is the highest
51
What is carboxylic acid
OH=C-O
52
What is an ester
O=C-O-CH3
53
What is acetic anhydride
Ch3-C(=O)-O-C(=O)-Ch3