Acid-Base Equilibria Flashcards

(44 cards)

1
Q

tastes sour and causes dyes to change colour

A

Acids

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2
Q

tastes bitter and feels soapy

A

Base

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3
Q

increases [H+] when dissolved in solution

A

Arrhenius Acid

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4
Q

increases [OH-] when dissolved in solution

A

Arrhenius Base

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5
Q

H+ donor; donates a proton

A

Bronsted-Lowry Acid

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6
Q

H+ acceptor; accepts a proton

A

Bronsted-Lowry Base

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7
Q

two formulas that differ by H+

A

Conjugate Acid-Base Pair

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8
Q

Conjugate ___ of a/an ___ has one fewer H+

A

base; acid

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9
Q

Conjugate ___ of a/an ___ has one more H+

A

acid; base

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10
Q

substance is one which can both donate and accept protons/hydrogen ions

A

Amphiprotic

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11
Q

substances has reactions as both acid and base

A

Amphoteric

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12
Q

All ____ substances are ____, but not all ____ substances are ____.

A

amphiprotic; amphoteric; amphoteric; amphiprotic

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13
Q

in water, few molecules act as bases and few act as acids

A

autoionization of water

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14
Q

Ion Product Constant (Kw)

A

Kw) = 1.0×10^(-14)

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15
Q

[H+] and [OH-] if a solution is neutral

A

[H+] = [OH-]

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16
Q

[H+] and [OH-] if a solution is acidic

A

[H+] > [OH-]

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17
Q

[H+] and [OH-] if a solution is basic

A

[H+] < [OH-]

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18
Q

formula for calculating pH

A

pH = -log[H+]

19
Q

formula for calculating [H+]

A

[H+] = 10^(-pH)

20
Q

formula for calculating pOH

A

pOH = -log[OH-]

21
Q

formula for calculating [OH-]

A

[OH-] = 10^(-pOH)

22
Q

relationship between pH and pOH

A

[H+][OH-] = 1.0×10^(-14)

pH + pOH = 14.00

23
Q

uses electrodes to indicate small changes in voltage to detect pH for accurate measurements

24
Q

give less accurate, but quick measurements; compound that has one colour in its acid form and another in its basic form

25
What are the common strong acids?
HCl, HBr, HI, HNO3, HClO3, HClO4, H2SO4
26
donates only one proton ex: HCl, HBr, HI, HNO3, HClO3, HClO4
monoprotic
27
donates two protons ex: H2SO4
diprotic
28
What are the common strong bases?
KOH, NaOH, Ba(OH)2, CsOH, Sr(OH)2, LiOH
29
strongest acid that can exist in an aqueous solution
H3O+
30
strongest base that can exist in an aqueous solution
OH-
31
formula for percent ionization
[H+]eq/[HA]initial × 100
32
Relationship between KA and Kb
Ka × Kb = 1.0×10^(-14)
33
shift in equilibrium causes by the addition of a compound having an ion in common with the dissolved substance
the common ion effect
34
resist a change in pH when small amounts of a strong base or strong acid is added
buffer solutions
35
Henderson-Hasselbalch Equation
pH = pKa + log([A-]/[HA]) [A-]/[HA] = antilog(pH-pKa) *pKa = -log(Ka)
36
technique used to determine the concentration of an unknown solution
Titration
37
solution of a known concentration which is added to another solution whose concentration has to be determined
Titrant
38
solution whose concentration has to be determined
Analyte or Titrand
39
point at which the amount of titrant added is enough to completely neutralise analyte solution; moles of base is equal to the moles of acids and the solution only contains salt and water
equivalent point
40
substance (weak acid or weak base) that is added to the analyte solution and changes colour at or near the equivalence point
indicator
41
point at which indicator changes colour in an acid-base titration
end point
42
equivalence point of strong acid and strong base titration
pH = 7
43
equivalence point of weak acid and strong base
pH > 7
44
equivalence point of strong acid and weak base titration
pH < 7