Acidification Flashcards

(41 cards)

1
Q

_____ _____= the settling, of deposition of acidic or acidic-forming pollutants from the atmosphere onto Earth’s surface

A

acid deposition

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2
Q

Acid deposition includes:
(list 4)

A
  • acid precipitation (rain, snow, sleet, hail)
  • acid fog
  • acidic gases
  • acidic dry particles
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3
Q

acid deposition is mostly caused by ____ activities, but can be ____
- it occurs when pH < ___

A

anthropogenic
natural

5.6

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4
Q

T/F
precipitation is naturally slightly acidic

What’s the usual pH of rain?

A

true!
rain pH= 5.6

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5
Q

What’s the first step in the acid deposition pathway?

A

SO2, CO2, and NOx emissions are released

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6
Q

What are the largest sources of carbon dioxide, sulfur dioxide and nitrogen oxides in Canada?

A

CO2: oil and gas industry

SO2: largest source is oil and gas industry

NOx: largest source is transportation

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7
Q

___ of CO2 released by burning coal, oil, & gas dissolves into the ocean

As a result, in the past 200 years, oceans have become __% more acidic

A

1/4

30%

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8
Q

What’s the second step in the acid deposition pathway?
How does it happen?

A

The pollutants are transformed into acid particles

  • Oxidizes in the atmosphere
  • oxidized form dissociates in water vapor (in the atmosphere) to release H+ and form acid
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9
Q

___ transport these acids long distances (no matter the source)- usually go toward the poles

A

winds

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10
Q

what’s the 3rd step in the acid deposition pathway?

A

the acid particles fall to the earth as wet or dry depositions

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11
Q

wet deposition=

A

acids removed from the atmosphere in the form of water (rain, snow, sleet, hail)

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12
Q

dry deposition=

A

acids removed from the atmosphere in the form of particulates or gases (no water).
- often in the form of fly ash, sulfates, nitrates, and SO2 and NOx gas

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13
Q

What is the 4th step in the acid deposition pathway?

A

May cause harmful effects to soils, forests, streams, lakes, and more
*some areas get the worst of it as it accumulates over time

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14
Q

List 3 ways in which acid deposition damages soils

A
  1. depletes calcium and other base cations (nutrients in the soil)
  2. mobilizes aluminum, heavy metals from soil to water
  3. accumulates sulfur, nitrogen in soils –> can lead to eutrophication
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15
Q

How does acid deposition damage forest ecosystems?
- list 1 direct effect and 1 indirect effect

A

direct effect: leaches Ca out of needles
- lose calcium in cell membranes= more susceptible to freezing, so they usually die in the winter

indirect effect: alters soil chemistry
- even less calcium to uptake, more toxic aluminum

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16
Q

Acid deposition causes increased leaching of ___ into surface waters as runoff from soils

A

aluminum

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17
Q

What happens to aquatic animals if the pH is too low in streams and lake ecosystems?

A

can be lethal
- can disrupt osmotic balance in fish, eventually leading to heart attacks

18
Q

Explain what happens to aquatic invertebrates (zooplankton) when streams and lake ecosystems acidify

A
  • usually, zooplankton take up calcium from the water to build their shells
  • but, if the water is acidic (therefore less Ca in the water), then the water takes back the calcium from the zooplankton, dissolving their shells
19
Q

What experiment helped us figure out that acidification is a huge problem?

A

The experimental acidification of Lake 302 and 223 at ELA in Ontario

20
Q

After lake 302 recovered from acidification, what happened to the phytoplankton species that were in the lake before acidification?

A

most of the species almost died off when it was very acidic, and once the lake was recovered back to normal pH, there was a slight shift in the species that returned

21
Q

zooplankton biomass overall ____ (inc/ dec) as lake 302 acidified

A

decreased
some species of zooplankton were more tolerant than others though

22
Q

T/F
all but 2 species of fish disappeared from lake 302 when it was acidified to pH= 4.6

Did they all return naturally once pH was brought back up?

A

false
all but 1 species! (meaning that 1 species is tolerant to acid)

No, they did not return naturally. They only returned because the lake was restocked.

23
Q

Which are acidifying faster- oceans or freshwater?

A

freshwater is acidifying faster

BUT oceans are still seeing a significant decrease in pH!

24
Q

Ocean pH is normally= __
- could go down to __ this century
- This would have a huge impact on ___

A

8
7.5

biodiversity

25
There have been 4 pieces of acid deposition legislation in Canada. List all 4 (names and dates)
1. 1985 Eastern Canada Acid Rain Program 2. 1991 Canada-US Air Quality Agreement 3. Canada-wide Acid Rain Strategy Post- 2000 (signed 1998) 4. 2004 Acid Rain Science Assessment
26
What did the 1985 Eastern Canada Acid Rain Program do?
- capped SO2 emissions in the 7 easternmost provinces (updated in 2000 to adjust cap on emissions) - established monitoring *this was the first time Canada stepped in and did something about the problem
27
What did the 1991 Canada-US Air Quality Agreement do?
- cut SO2 and NOx emissions in CAN and US - increased monitoring
28
What did the Canada-wide Acid Rain Strategy Post- 2000 (signed 1998) do?
- continued reductions in SO2 emissions - even more monitoring - regulate reports to public- must be accessible - prevent clean/ undamaged areas from being degraded (+start recovery)
29
What did the 2004 Acid Rain Science Assessment find?
- need to reduce emissions even further (stricter caps) - need to address acidification in the west & north (where the most emissions happen)
30
There are 2 parts to ecosystem recovery from acid deposition: 1. ____ recovery 2. ____ recovery
chemical biological (can't happen until chemical recovery is well underway)
31
chemical recovery=
decrease in damaging [chemical] in soils and waters. if the decrease is sufficient, pH will increase *chemical recovery must begin before biological recovery can start
32
Biological recovery=
*can't begin until chemical recovery is well underway = multi-step return and/or increase in health or organisms in previously acidified ecosystems
33
Is chemical recovery occurring? What is the rate of chemical recovery dependent on?
yes! rate depends on resistance on the ecosystem to acid deposition- determined by the amount of calcium naturally found in soils and surface waters
34
If an ecosystem has lots of ____, it's most resistant/ resilient to acid rain
calcium
35
If an ecosystem has low Ca, it's less resistant/ resilient to ____ ____
acid deposition *if Ca has been depleted, ecosystem takes a really long time to recover
36
202 lakes were originally targeted in ___ with legislation. __% have reduced acidity :) 56% show ___ _____ __% have increased acidity :(
1985 33% no change 11%
37
Do soils appear to be chemically recovering?
yes, but slowly - further acidification isn't occurring - pH slowly increasing again - Al levels decreasing
38
Is biological recovery occurring?
probably, but slowly data is still limited
39
____ recover faster from acidification because they have a short life _____ (like __)take a long time to biologically recover
microorganisms macroorganisms like trees
40
why is it hard to tell is recovery is happening?
it takes several years for recovery to happen- we only started paying attention to acidity in the 1990's, so we need more time to tell
41
- It can take __+ years for zooplankton to recover from acidification - 10-20+ years for ___ populations to recover - >__ years for trees to recover
10 fish 20