acids and bases Flashcards
(21 cards)
define an acid
a substance that dissociates to form H⁺ ions in aqueous solutions (when dissolved in water)
physical properties of an acid
- have a sour taste
- is corrosive in large amounts or
with a high concentration - can conduct electricity when aqueous due to H⁺ ions
chemical properties of an acid
- low pH value (<7)
- turn blue litmus paper red
- only shows acidic properties when dissolved in water
- react with reactive metals (e.g. sodium, magnesium)
define a base
a metal oxide or hydroxide, must contain the O²⁻ or OH⁻ ions
define an alkali
a sub-category of a base that is soluble in water and can completely dissolve
physical properties of an alkali
- have a bitter taste
- feel slippery and soapy to touch
- is corrosive in large amounts or with a high concentration
- dissociate in water to conduct electricity due to OH⁻ ions
chemical properties of an alkali
- high pH value (>7)
- turn blue litmus paper red
- only shows alkaline properties when dissolved in water
- reacts with acids
acid-metal reaction
metal + acid → salt + hydrogen [MASH]
acid-base reaction (neutralisation)
acid + alkali / base → salt + water [AASW]
acid-carbonate reaction
acid + carbonate → salt + water + carbon dioxide [CASH₂OCO₂)
alkali-ammonium salt reaction
alkali + ammonium salt → salt + water + ammonia [AAmSWAm]
metals that do not react with any acids
- inert metals such as copper, silver or transition metals
- lead does not react with hydrochloric acid, sulfuric acid because of protective lead (II) layer formed
test for carbon dioxide
- bubble gas into limewater using a delivery tube
- if carbon dioxide is present, a white precipitate will be formed
test for hydrogen gas
- place a lighted splint at the mouth of the test tube
- if hydrogen gas is present, splint will be extinguished with a soft ‘pop’ sound
define strength of acid/alkali
- extent of ionisation of an acid/alkali when dissolved in water
- note: strength does not change with volume or concentration
define strong acid/alkali
- acid/alkali that completely ionises in an aqueous solution
- highly corrosive, do not touch
- e.g. hydrochloric acid, sulfuric acid, nitric acid, sodium hydroxide
define weak acid/alkali
- acid/alkali that only partially ionises in an aqueous solution
- if it’s edible or a household product, it’s usually weak
- e.g. ethanoic acid, citric acid, lactic acid, ammonia
function of indicators
- substance that changes the colour depending on whether an acidic or alkali substance is added to it
- gives different colours according to the pH value
universal indicator scale
- acid: red, orange and yellow (pH 0 to 6)
- neutral: green (pH 7)
- alkali: dark green, blue, indigo, violet (pH 8 -14)
other common indicators
- methyl orange: turns from red to yellow (pH 3 to 5)
- screened methyl orange: turns from violet to green (pH 3 to 5)
- litmus: turns from red to blue (pH 5 to 8)
- thymolphthalein: turns from colourless to blue (pH 9 to 10.5)
hydrogen ion concentration of aqueous solutions
- pH <7: concentration of H⁺ ions is higher than OH⁻ ions (acidic)
- pH 7: concentration of H⁺ ions is equal to OH⁻ ions (neutral)
- pH >7: concentration of H⁺ ions is lower than OH⁻ ions (alkaline)