Acids and bases Flashcards

1
Q

Acid + Metal –>

A

Salt + Hydrogen

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2
Q

Acid + Metal Oxide –>

A

Salt + Water

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3
Q

Acid + Metal Hydroxide

A

Salt + Water

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4
Q

Acid + Metal carbonate

A

Salt + CO2 + H2O

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5
Q

Define an acid

A

Proton donor

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6
Q

Define a base

A

proton acceptor

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7
Q

What does amphoteric mean?

A

Water can act as either an acid or a base

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8
Q

How to calculate pH

A

-log[H+]

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9
Q

How to calculate [H+] using pH

A

10^-pH

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10
Q

Key points for the pH scale

A

The smaller the pH, the greater the concentration of H+ ions. A differnce of 1 on the scale means a differnce in x10 of [H+]

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11
Q

Define a strong acid

A

Fully dissociates

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12
Q

What does Ka stand for

A

equilibrium constant in terms of acid dissoiation

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13
Q

Ka equation

A

products over reactants

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14
Q

What is the differnce between monoprotic, diprotic and triprotic

A

Te amount of [H+] ions it contains
x1
x2
x3

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15
Q

Define a weak acid

A

Only partially dissociates

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16
Q

Ka for weak acid

A

[H+][A-]/[HA]

17
Q

What type of acid is a craboxyllic acid

18
Q

H+ using Ka

A

(square root)Ka[HA]

19
Q

pKa equation

20
Q

Ka using pKa

21
Q

Kw expression

22
Q

H+ using Kw

A

Square root of Kw

23
Q

PH changes with temperature

A

At temp higher than 298K, equilibrium shifts to the right in the endothermic direction to oppose change. [H+] increases. However does not mean it goes more acidic as [H+]=[OH]-

24
Q

Calculating pH

25
State why calibrating a pH meter just before it is used improves the accuracy of the pH measurement
After storage, it will not provide the right reading
26
describe how you would obtain the pH curve for the titration
measure pH of acid, add alkali, stir, measure pH after each addition- repeat until in excess
27
suggest why the conc of NaOH in a solution slowly decreased when left open in air
Reacts with Co2 in the air
28
Explain why the temp rise is less
same amount of Q distributed over a larger volume
29
pH of magnesium hydroxide compared to calcium
lower- Mg is less soluble
30
Draw the displayed formula of H2SO4
31
explain why H2O is not shown in the Kw expression
[H2O] is constant
32
suggest why the pH probe is washed with distilled water between each measurement
to reduce contamination
33
explain why the volume of NaOH added between each pH is smaller as the end point is approached
to avoid missing endpoint
34
suggest a suitable piece of apparatus that could be used to measure out the sodium hydroxide solution, explain why this apparatus is more suitable than a pipette
burette- can deliver variable volumes
35
why would the end point of the graph is difficult to judge accurately
the change in pH is gradual, would change colour over a range of volumes
36
a practical procedure to obtain data that a graph could be plotted from
place in a fixed volume of alkali in a flask or beaker. add acid in small portions from burette, stir and use pH meter to record pH after each decision
36
suggest how the practical procedure could be refined
repeat with indicator- select the indicator that changes colour rapidly from pH 7 to 4