acids and bases Flashcards

1
Q

bases soluble in water

A

are alkalis

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

zinc hydroxide

A

Zn(OH)2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

acid definition

A

any substance that adds H+ ions to water
-proton donor

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

hydronium ions

A

hydrogen atoms attach to h2o molecule to form H30

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

base definition

A

proton acceptor

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

weak acids

A

only a few molecules dissaaociste into ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

strong acids

A

molecules completely dissociate into ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

strong base

A

fully dissociate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

weak bases

A

react with water to form equilibrium with h2o

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

conjugate acid

A

base plus h+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

conjugate base

A

acid reacting with base and donating proton

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

equation for concentration

A

moles of ion concentration/ volume of solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

pH =

A

-log10(H+)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

increasing conc if acid

A

decreases pH value

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

pH of strong acid

A

-log10(H+)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

conc of strong acid

A

(H+) = 10-pH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

moles with conc and volume

A

conc times volume

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

acid solution + aqueous base when calculating new pH

A

find change in volume
-find change in (H+)

19
Q

Kc =

A

products over reactants

20
Q

Kw =

A

H+ times OH-
units mol 2 dm-6

21
Q

equation for dissociation of water

A

H2O – H+ + OH-

22
Q

Kw at room temp

A

1 times 10-14

23
Q

temperature effect on kW

A

decreases if H and OH decrease and if conc of H and OH increase it increases

24
Q

why does Kw change when temp increases

A

because equilibrium shifts to right so conc of H and OH produced increases so larger number brings value of Kw up and goes down if conc decreases
-position shifts to right because ionisation of water endothermic

25
how to find conc of H+ ions in equation
-H and OH equals H squared -to find H conc you have to square root KW value
26
why is pure water always neutral
hydrogen ions always equal to amount of hydroxide ions
27
how to work out conc of OH or H when kW given and one other concentration given
Kw divided by other concentration
28
what doesnt affect Kw value of pure water
conc of H and OH ions -addition of base to water -addition of acid to water pH
29
finding pH of strong acid
-log10 H+
30
finding pH of strong base
-first find the concentration of OH ions using dissociation equation -find conc of H+ of ions -use Kw to find it - rearrange equation of Kw -
31
dissociation of NaOH
NaOH = Na+ + OH-
32
calculating conc of strong base
use pH to find conc of H ions -10-ph -use Kw to find conc of OH ions -OH = Kw/ H+
33
pH and group 2 hydroxides
times by 2 because 1-2 ratio
34
solubility going down group 2
increases
35
factors that affect pH of solution
amount of dissociation -solubility -concentration of H+ ions -temperature
36
calculating what mass of molecule dissolved into water
-use pH to find conc of solution --logH+ -then OH= Kw/ H+ -rearrange to get moles= conc times volume -mass= moles times molar mass
37
calculating final pH of two solutions
-find moles of both compounds -which one is in excess- calculate limiting compound leftover after reaction -find conc of limiting in final solution -use Kw to find conc of opposite ion in final solution -use conc to find pH
38
whats a buffer
resists change in pH when small amounts of acid are added to it or base
39
what must buffer solutions have
high concentrations of undissociated acids and high concs of its conjugate base
40
exam question how does a buffer resist changes in pH upon addition of a small amount of acid
write down reversible reaction for specific buffer state that adding acid increases H+ state that equilibrium shifts to the left to lower the conc of H+ state that overall H+ remain almost constant
41
exam question how does a buffer resist changes in pH upon addition of small amount of base
write down reversible reacrtion for specific buffer state that reacrion takes place between OH- and H+ which lowers the conc of H+ ions in buffer solution state that equilibrium shifts to right to replenish lost H+ state that overall H+ remains almost constant
42
use of buffers in real life
brewing of beer blood- hydrogencarbonate swimming pools
43
alkaline buffers
weak base and conjugate acid pH below 7
44