Acids And Bases Flashcards
(24 cards)
What is the Arrhenius definition of a base?
It is a substance that dissolves is water to produce OH- ions
What is the Arrhenius definition of an acid?
It is a substance that dissolves in water to produce H+ (H3O+) ions
What is a Bronster-Lowry Acid?
It is a proton donor
What is a Brønsted-Lowry base?
It is a proton acceptor
What is a conjugate acid-base pair?
Any pair of molecules or ions that can be interconverted by transfer of a proton (aka when an acid turns into its conjugate base or when a base turns into its conjugate acid)
What do strong acids and bases do in water?
Completely ionize
What do weak acids and bases do in water?
Partially ionize
Pka=?
-logKa
Stronger acids have _____Ka values and therefore ______pKa values
- ) Larger
2. ) Smaller
Some common weak organic acids are:
- Carboxylic acids
- Compounds containing the -COOH group (carboxyl)
The position of equilibrium in an acid base reaction favors reaction of the _____ acid (____pKa value) with the _____base to form the ______ acid (______pKa value) and the _____ base.
- ) Stronger
- ) Lower
- ) Stronger
- ) Weaker
- ) Higher
- ) Weaker
What is thermochemistry?
The study of energy of the entire system at each moment of a reaction
If the products are more stable than reactants, the overall thermodynamics are favorable for reaction and the step is ______
Exergonic
If products are less stable than reactants, the overall thermodynamics are not favorable for reaction and the step is ______
Endergonic
What is kinetics?
The study of rates of chemical reactions
The lower the free energy of activation, the _____ the rate of the reaction
Faster
What is enthalpy?
It is the energy contained within chemical bonds and solvation
What happens in an exothermic reaction?
Heat is released because bonds are formed in the product that are stronger than the bonds that were broken in the starting material
What happens in an endothermic reaction?
The bonds formed in the product are weaker than those broken in the starting materials, so heat is absorbed
What is entropy?
Entropy is the measure of chaos
What is a Lewis Acid?
It is a species that can form a new covalent bond by accepting a pair of electrons
What is a Lewis Base?
It is a species that can form a new covalent bond by donating a pair of electrons
All Brønsted-Lowry acids (_____) are also Lewis acids
Proton donors
All Bronster Lowery bases (________) are also Lewis Bases
Proton acceptors