Acids And Bases Flashcards

0
Q

What is a Brønsted-Lowry base?

A

Proton (H+) acceptor

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1
Q

What is a Brønsted-Lowry acid

A

Proton (H+) donor

HCl

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2
Q

What is a Lewis acid?

A

Electron pair acceptor

NH3

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3
Q

What is a Lewis base?

A

Electron pair donor

Cu2+

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4
Q

Are all Brønsted-Lowry acids Lewis acids?

A

Yes

Lewis acids do not have proton transfer

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5
Q

Litmus in acid and alkali

A

Acid - pink

Alkali-blue

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6
Q

Methyl orange color in acid and base

A

Acid-red

Alkali-yellow

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7
Q

Phenolphthalein colour in acids and alkali

A

Acid-colourless

Alkali-pink

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8
Q

What is a base?

A

Substance that accepts H+

Metal oxides/hydroxides
Ammonia
Soluble carbonates/ hydrogen carbonates

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9
Q

What is an alkali ?

A

Alkalis form OH- ions

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10
Q

Acid + metal –>

A

Acid + metal –> salt + hydrogen

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11
Q

Acid + base –>

A

Acid + vase –> salt + water

Neutralization reaction

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12
Q

Acid + carbonate –>

A

Acid + carbonate –> salt + water + carbon dioxide

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13
Q

How to distinguish between strong and weak acids and bases

3 ways

A

Electrical conductivity
Strong high

Rate of reaction

pH

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14
Q

Weak acids

A

Ethanoic (organic)

Carbonic (H2CO3)

Phosphoric (H3PO4)

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15
Q

Strong acids

A

Hydrochloric

Nitric (HNO3)

Sulfuric

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16
Q

Strong bases

A

Li/Na/K/Ba hydroxide

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17
Q

Weak acids

A

Ammonia

Ethylamine

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18
Q

How difference between strong and weak acids?

A

Strong acids/bases- almost complete dissociation in solution

Weak-partially dissociate in solution

19
Q

What is a change in 1 pH in H+?

20
Q

pH =

A

pH= - log [H+]

H+ = 10^-pH

21
Q

What is Kw?

A

Ionic product constant of water

Kc [H2O] = [ H+] [OH-]

22
Q

What affects KW?

A

Temperature dependent (equilibrium constant)

Increase temperature increases kW

  • more dissociation
  • endothermic
23
Q

Find H+ of pure water

A

H+ = square root KW

24
At 25c Find pOH knowing pH
pH + pOH = 14
25
Find pH from pKw
pH + pOH = pKw
26
What is Ka?
Ka = [H3O+] [A-] / [HA] Concentration of ions/ dissociation -acid dissociation constant
27
What affects Ka?
- temperature | - acid
28
What is Kb?
Kb = [BH+] [OH-] / [B] Base dissociation constant
29
What is a larger pKa?
Weaker acid
30
Relationship between acid and conjugate base
Strong acid = weak conjugate base
31
Organize acid strong to weak:
B&j jhhhh
32
What is a buffer solution?
Resistant to change in pH When adding a Small amounts if acid/alkali
33
Composition of acidic buffers
Weak acid (ch3cooh) Salt of weak acid+strong alkali (Nach3coo) Fully Dissociates to CH3COO-
34
What happens in acidic buffer adding H+
Reacts with base H+ + CH3COO- CH3COOH
35
What happens add OH- in acidic buffer?
OH- reacts with acid CH3COOH + OH- CH3COO- + H2O
36
Composition of basic buffer?
Weak base (NH3) Salt of weak base+strong acid (NH4Cl) Fully dissociates to NH4+
37
Determine pH of buddy solution
Bffbdbgddb
38
Find pH
pH =pKa + log[salt]/[acid]
39
In buffer when does pH=pKa and pOH=pKb
[acid]=[salt] [base]=[salt]
40
How to make buffer
Jfjdjhhe
41
Factors affect buffers
Temperature - change Ka/ kb, changes pH Not dilution- not change pH but buffer capacity
42
What is the equivalence point ?
In titration Stoichiometrically equivalent amount avid and base Salt and water only
43
Strong acid and base
Equivalence - 7 Initial pH 1 PH changes gradually to equivalence Ph jump 3-11 at equivalence Curve flattens at high pH
44
Weak acid strong base
Equivalence - >7 Initial pH girly high 3 Stays constant until equivalence Jump form 7-11 at equivalence Curve flattens at high pH 13