Acids and Bases Flashcards
POlyprotic Acids
Contain more than 1 H
Increasing H atom= easier to dissociate= Increase acid strength
Rule only applies to polyprotic acids
(H2SO4 stronger than SHO4-, but not stronger than HCl)
H2SO4
Only strong polyprotic acid
Strong Acids
HCl HBr HI HNO3 HClO4 H2SO4
Strong Bases
LiOH
KOH
Ca(OH)2
Mg(OH)2
Trends- Increasing acicity=
Increase KA=
Decrease pKa=
Decrease pH
Trends- Increasing alkalinity=
Increase Kb=
Decrease pKb=
Increase pH
BL Acids
H+ donor
Needs H
BL Base
H acceptor
Needs lone pair
Conjugate Acid
Base+ H
Strong base= weak CA
Conjugate Base
Acid after losing H
Strong acid= weak CB
Arrhenius acid/bases
Same as BL, but are H+ donors/acceptors in aquesous solution
Lewis Acids
Electron pair acceptors
Contain valence orbitals
Lewis Base
Electron pair donors
Contain lone pair
Strong Acid+ Strong Base=
Neutral salt
Strong Acid + Weak Base
Acidic salt
Weak Acid + Strong Base
Basic salt
Weak Acid + Weak Base
Reaction does not go to completion
Amphoteric Salts
Have both acidic and basic properties
Can behave as either acids or bases
i.e. (Al(OH)4
Buffers
Solution that resists pH change
Acidic components reacts with OH when strong base is added
Basic component reacts with H+ when strong acid is added
Buffer Can Be Formed By
WA + BB
SA + WB
SB + WA