ACS Final 2015 Flashcards

(60 cards)

1
Q

How to find Kw

A

[H30+][OH-]=1.0*x10^14

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2
Q

How to find Kw

A

[H30+][OH-]=1.0*x10^14

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3
Q

How to find pKa

A

-log(Ka)

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4
Q

[H3O+]

A

Square root of (Ka)(initial concentration)

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5
Q

STRONG ACIDS

A

HCl, HBr, HI, HClO4, H2SO4, HNO3

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6
Q

Weak acids Ka…

A
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7
Q

Weak acid + strong base pH …

A

> 7

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8
Q

Strong acid + weak base titration pH…

A
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9
Q

Buffer equation

A

pH=pKa + log([salt]/[acid])

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10
Q

Ka =

A

Concentration of products divided by concentration of reactants

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11
Q

1st Law of Thermodynamics

A

mass is neither created nor destroyed

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12
Q

2nd Law of thermodynamics

A

entropy will always increase in the natural world

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13
Q

3rd Law of thermodynamics

A

A perfect crystalline solid is 0 K

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14
Q

Enthalpy

A

heat is absorbed

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15
Q

Delta H

A

Exothermic

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16
Q

Delta H > 0

A

Endothermic

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17
Q

Entropy

A

disorder of a substance

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18
Q

+delta S

A

More randomness

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19
Q

Gibbs Free Energy

A

⋀G=⋀H-T⋀S

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20
Q

⋀G +

A

SPONTANEOUS

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21
Q

⋀G -

A

Non-spontaneous

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22
Q

Gas equilibrium constant

A

⋀G = -RTln(K)

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23
Q

Low Ksp

A

Low solubility

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24
Q

Le Chât’s Principle

A

Equilibrium will shift in response stop temperature, pressure or concentration

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25
[H3O+]
Square root of (Ka)(initial concentration)
26
STRONG ACIDS
HCl, HBr, HI, HClO4, H2SO4, HNO3
27
Weak acids Ka...
28
Weak acid + strong base pH ...
> 7
29
Strong acid + weak base titration pH...
30
Buffer equation
pH=pKa + log([salt]/[acid])
31
Ka =
Concentration of products divided by concentration of reactants
32
1st Law of Thermodynamics
mass is neither created nor destroyed
33
2nd Law of thermodynamics
entropy will always increase in the natural world
34
3rd Law of thermodynamics
A perfect crystalline solid is 0 K
35
Enthalpy
heat is absorbed
36
Delta H
Exothermic
37
Delta H > 0
Endothermic
38
Entropy
disorder of a substance
39
+delta S
More randomness
40
Gibbs Free Energy
⋀G=⋀H-T⋀S
41
⋀G +
SPONTANEOUS
42
⋀G -
Non-spontaneous
43
Gas equilibrium constant
⋀G = -RTln(K)
44
Low Ksp
Low solubility
45
How to find K
[B]^b/[A]^a
46
Le Chât's Principle
Equilibrium will shift in response stop temperature, pressure or concentration
47
When AB adding A will...
Cause it to shift to B
48
Lowering temp (exothermic)
Shift toward product
49
Lowering temp (endothermic)
Shift toward reactant
50
First order-
ln[A] vs. time
51
Second order-
1/[A] + kt
52
Zero order-
-kt + [A]
53
Arrhenius equation-
l=Ae^(-Ea/RT)
54
Boyle's law
PxV
55
Charles's Law
V/T
56
Volume/temp proportion
v1t2=v2t1
57
Avagadro's Law
V/n
58
IDEAL GAS LAW
pV=nRT
59
Partial Pressures
P(total)= p1+p2+p3....
60
Mole fraction=
x/x+y+z