Additional notes Flashcards

(34 cards)

1
Q

Water can act as both an acid and a base making it

A

amphoteric

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2
Q

If the number of hydrogen that was given was for a base what are you actually solving for

A

Potential of hydroxide

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3
Q

What is considered as weak acid

A

3-6

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4
Q

what is considered as a strong base

A

11-14

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5
Q

What is considered as a strong acid

A

3 below

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6
Q

what is considered as a weak base

A

8-10

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7
Q

Why should water be added first before acids

A

It will cause an explosion due to exothermic reactions

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8
Q

What does weight accurately mean

A

Using analytical balance

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9
Q

Is it necessary to perform titration with blank

A

yes

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10
Q

Common name of barium hydroxide

A

Baryte

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11
Q

what is carbonate error

A

refers to how reactive OH is to carbon atoms, which may alter the concentration of OH

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12
Q

Why polyolefin containers

A

To prevent leeching

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13
Q

Why are the primary standards dried

A

to remove impurities

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14
Q

sonication / water bath

A

the process done to prevent carbonate error

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15
Q

Why does some titration need residual titration

A

Insoluble
Sharp-end point
Slow
Volatile

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16
Q

Importance of filter

A

separates the intermediates

17
Q

What temperature is Ignition conducted

18
Q

Why should zinc oxide be ignited first

A

should can react with carbon dioxide to form zinc carbonate

19
Q

Why is ammonium chloride added in assay of Zinc oxide

A

To separate undissolved components

20
Q

Why should zinc oxide assay need to be gently heated

A

necessary to increase the rate of reaction between zinc oxide and sulfuric acid

21
Q

Why should boric acid by dried and accurately weighed

A

To ensure that H3BO3 will be free from moisture and the exact amount of H3BO3 will be used in the assay

22
Q

Why is boric acid dissolved in glycerin

A

boric acid is a weak acid to be titrated quantitatively in an aqueous solution with an alkali with a visual indicator, however, it can be titrated with a standard alkali in the presence of polyhydric alcohol using phenolphthalein as an indicator. Boric acid is esterified in the presence of polyhydric alcohols such as glycerol or mannitol, forming a monobasic acid that is strong enough to give a satisfactory endpoint (Glycerin makes the boric acid strong so that it may readily react with the titrant NaOH)

23
Q

Why is concentration of sugar alcohol be at least 30%

A

to prevent complex acid

24
Q

Why is glycerin used in boric acid

A

forms a slightly dissociated complex with the metaborate ion which prevent the reversal of the reaction

25
Glycerin should be neutralized with 1 N NaOH
Since it imparts acidity to the solution and thus may increase consumption of the VS
26
Aspirin by nature is an ester as such:
it is readily hydrolyzed when come in contact with water
27
What should you use to measure aspirin
weighing bottle, to reduce exposure to air
28
What type of titrant is the 0.5 N sodium hydroxide in Aspirin
excess titrant
29
What type of titrant is the 0.5 N sulfuric acid in Aspirin
Back titrant
30
Importance of blank titration:
for correction of data
31
Why should aspirin be diluted in sodium hydroxide
Since it is a weak acid
32
Residual titration of acidimetry
* Assay of Milk of Magnesia * Assay of Methenamine * Assay of Ammonium Chloride Injection * Assay of Zinc Oxide
33
For nitrogen determination (in organic substances plus the nitrogen contained in the inorganic compounds ammonia and ammonium)
Kjeldahl Method
34
Residual Titration for alkalimetry
Assay of Aspirin