Aldehydes and ketones (Lab) Flashcards

(33 cards)

1
Q

What is the functional group of aldehyde?

A

R-CHO

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2
Q

The simplest member of RCHO

A

HCHO = methanal or formaldehyde

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3
Q

Which is more reactive: Aldehyde or ketone?

A

Aldehyde

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4
Q

What is the formula of formaldehyde?

A

HCHO

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5
Q

What do you call HCHO dissolved in water? This is also often used to embalm dead bodies

A

Formalin

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6
Q

It is an aldehyde that is colorless wuth a pungent smell, irritating odor

A

HCHO

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7
Q

An aldehyde with a chico-like odor and is soluble in water

A

CH3CHO

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8
Q

An aldehyde with a clear colorless liquid with an almond-like smell. It is often used as food additive

A

Benzaldehyde

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9
Q

The simplest aromatic aldehyde

A

Benzaldehyde

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10
Q

What is the formula of benzaldehyde?

A

C6H5CHO

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11
Q

True or false: Aldehydes and ketones are functional isomers

A

True

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12
Q

What is the functional group of ketone?

A

R-CO-R

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13
Q

It resists polymerization and is not easily oxidized

A

Ketones

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14
Q

It gives negative results with Fehling’s, Tollen’s, and other mild oxidizing agents

A

Ketone

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15
Q

An organic compound with the formula (CH3)2CO

A

Acetone

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16
Q

It is the simplest and smallest ketone

17
Q

It is a clear colorless flammable liquid with a pleasant, somewhat fruityodor, melting at -95.4 °C and boiling at 56.53 °C w/ sharp biting taste

18
Q

A type of ketone that is highly flammable & burns with luminous flame

19
Q

The positive result of 2,4-dinitrophenyl hydrazine test (DNP)

A

yellow to orange to red ppt

20
Q

The positive result of NaHSO3 Test

A

white crystalline ppt

21
Q

What is the composition of schiff’s test reagent?

A

fuchsin dye + SO2

22
Q

What is the positive result of schiff’s test?

A

purple (magenta) in aliphatic & aromatic aldehydes; pale pink with ketones

23
Q

What happens to schiff’s test if aldehyde is present?

A

The color is magenta

24
Q

What is the composition Fehling’s test?

A

A = CuSO4 (blue solution)
B = Na-K tartrate or Rochelle salt

25
The positive result of Fehling's test
brick red ppt. , Cu2O
26
What is the role of aldehyde in fehling's test?
Reducing agent
27
What is the composition of tollen's test?
AgNO3 + NH4OH
28
The positive result of tollen's test
Silver mirror, Ag0
29
The appearance of red colorations shows presences of _____ in sodium nitroprusside test
Ketone
30
The formula of sodium nitroprusside test
(Na2 [Fe(CN)5NO].2H2O)
31
The positive result of sodium nitroprusside
blood red that changes to wine red upon the addition of acetic acid
32
The positive result of Iodoform test
Yellow ppt
33
The result of autooxidation of benzaldehyde
White crystals