Aliphatic Organic

Question 1

Acyl chloride > 2 Amide

Answer 1

RNH2, reflux, RTP (Acylation)

Question 2

Acyl chloride > Ester

Answer 2

1 Alcohol, RTP (Acylation)

Question 3

Amide > Carboxylic acid

Answer 3

Dilute HCl (Acid hydrolysis)

Question 4

Acyl chloride > 1 Amide

Answer 4

concentration NH3, RTP (Acylation)

Question 5

Acyl chloride > Carboxylic acid

Answer 5

Water, RTP (Acylation)

Question 6

Carboxylic acid > Acyl chloride

Answer 6

SOCl2, RTP

Question 7

Ester > Carboxylic acid

Answer 7

H+ catalyst, RTP

Question 8

Carboxylic acid > Ester

Answer 8

1 Alcohol, H+ catalyst, RTP (Esterification)

Question 9

Ester > 1 Alcohol

Answer 9

H+ catalyst, RTP

Question 10

1 Alcohol > Ester

Answer 10

Carboxylic acid, H+ catalyst (Esterification)

Question 11

Carboxylic acid > Aldehyde

Answer 11

LiAlH4, dry ether (Reduction)

Question 12

Aldehyde > Hydroxynitrile

Answer 12

H2SO4, KCN/HCN, RTP (N.A.)

Question 13

Aldehyde > Carboxylic acid

Answer 13

K2Cr2O7, H+ catalyst, reflux (oxidation)

Question 14

1 Alcohol > Aldehyde

Answer 14

K2Cr2O7, H+ catalyst, distillation (oxidation)

Question 15

Nitrile > Carboxylic acid

Answer 15

H2SO4, reflux (Acid hydrolysis)

Question 16

Haloalkane > Grignard

Answer 16

Mg, dry ether, reflux

Question 17

Grignard > Carboxylic acid

Answer 17

CO2

Question 18

Haloalkane > 1 Amine

Answer 18

conc NH3, ethanol, high pressure (N.S.)

Question 19

Nitrile > 1 Amine

Answer 19

H2, Pt catalyst (Reduction)

Question 20

Haloalkane > 1 Alcohol

Answer 20

NaOH (N.S.)

Question 21

Haloalkane > Nitrile

Answer 21

KCN/HCN, ethanol (N.S.)

Question 22

1 Alcohol > Alkene

Answer 22

Excess H2SO4, heat (Elimination)

Question 23

1 Alcohol > Haloalkane

Answer 23

HX, H2SO4 catalyst

Question 24

Alkene > 1 Alcohol

Answer 24

H3PO4, steam, 300C

Question 25

Ketone > 2 Alcohol

Answer 25

LiAlH4, dry ether (Reduction)

Question 26

2 Alcohol > Ketone

Answer 26

K2Cr2O7, H+ catalyst, reflux (oxidation)

Question 27

Ketone > Hydroxynitrile

Answer 27

H2SO4, KCN/HCN, RTP (N.A.)

Question 28

Alkylhydrogensulfate > 2 Alcohol

Answer 28

H2O

Question 29

Haloalkane > 2 Alcohol

Answer 29

NaOH, reflux (N.S.)

Question 30

Alkene > Haloalkane

Answer 30

HX (E.A.)

Question 31

Alkene > Alkylhydrogensulfate

Answer 31

H2SO4, RTP

Question 32

Alkene > Dihaloalkane

Answer 32

X2 (E.A)

Question 33

Alkene > Diol

Answer 33

KMNO4, H2O

Question 34

Alkene > Alkane

Answer 34

H2, Ni catalyst, heat

Question 35

Alkane > Alkene

Answer 35

Cracking, heat

Question 36

Alkane > Haloalkane

Answer 36

HX, UV (Free radical substitution)

Question 37

Alkene > Polyalkene

Answer 37

High pressure

Question 38

Free radical substitution

Answer 38

Initiation: Cl2 > 2Cl* Propagation 1: Cl* + C4H10 > C4H9* + HCl C4H9* + Cl2 > C4H9Cl + Cl* Termination: 2Cl* > Cl2 2C4H9* > C8H18 Cl* + C4H9* > C4H9Cl

Question 39

Haloalkane > Alkene

Answer 39

NaOH Elimination