Alkene Addition Flashcards by Heather Bryant

Q

halohydrin adds what

A

X + OH

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

halohydrin regiochem

A

markovnikov

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

halohydrin stereochem

A

anti addition

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

halohydrin intermediate

A

bromonium or chloroinuium ion

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

halohydrin reagent

A

X2/H20

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

epoxidation does what

A

3 membered ring with o

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

epoxidation reagent

A

MCPBA or RCO3H

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

epoxidation stereochem

A

syn addition and flip products upside down

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

anti-dihydroxylation adds what

A

OH + OH

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

anti-dihydroxylation stereochem

A

anti addition

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

anti-dihydroxylation reagent

A

RCO3H or MCPBA / H3O+, H20

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

Acid-catalyzed hydration adds what

A

H + OH

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

acid-catalyzed hydration regiochem

A

Markovnikov

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

acid-catalyzed hydration stereochem

A

all

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

acid-catalyzed hydration intermediate

A

carbocation

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

acid-catalyzed hydration reagent

A

H3O+ or H2SO4 / H20

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

hydrohalogenation adds what

A

H + X

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

hydrohalogenation regiochem

A

markovnikov

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

hydrohalogenation intermediate

A

carbocation

How well did you know this?

1

Not at all

2

3

4

5

Perfectly

Q

hydrohalogenation stereochem

Study These Flashcards

A

all

Q

hydrohalogenation reagent

Study These Flashcards

A

HX

Q

oxymercuration-demercuration adds what

Study These Flashcards

A

H+OH

Q

oxy-dem regiochem

Study These Flashcards

A

markovnikov

Q

oxy-dem intermediate

Study These Flashcards

A

bridged mercurinium ion, radical

oxy-dem reagent

1)Hg(OAc)2, H20 / 2) NaBH4

oxy-dem stereochem

flip product upside down if chiral, all bc of radican

hydroboration oxidation adds what

H+OH

hydroboration oxidation regiochem

anti-Markovnikov

hydroboration oxidation sterochem

syn addition

hydroboration oxidation intermediate

BOOH complex

hydroboration oxidation reagent

1) BH3 THF / 2) H202, NaOH

Catalytic hydrogenation adds what

H+H

catalytic hydrogenation stereochem

syn addition

catalytic hydrogenation reagent

H2/Pdc, Pt, Ni, or Rh

halogenation adds what

X + X

halogenation stereochem

anti addition and flip products upside down

halogenation intermediate

bromonium 3 membered ring

Syn dihydroxylation adds what

OH + OH

syn dihydroxylation stereochem

syn addition

syn dihydroxylation intermediate

cyclic osmate ester

syn dihydroxylation reagent

1) OsO4/ 2) NMO or NaHSO4, H20 or KMnO4/cold

ozonolysis does what

cleave double bond to produce ketones and aldehyde or carboxylic acids

ozonolysis reductive

Zn or DMS reagent, aldehyde, keeps H

ozonolysis oxidative

H2O2 reagent, if H is there add O

ozonolysis intermediate

molozonide and ozonide

Hydrohalogenation w/ ROOR adds what

H + X

hydrohalogenation w/ ROOR regiochem

anti-Markovnikov

hydrohalogenation w/ ROOR intermediate

radical

hydrohalogenation w/ ROOR reagent

HX/ROOR