Alkenes Flashcards
(15 cards)
Are alkenes saturated or unsaturated
Unsaturated
What is the alkene functional group
C=C
How is a Pi bond formed
Sideways overlap of two P-orbitals
How is a Sigma bond formed
Head on overlap of orbitals
Why are alkenes reactive
- The Pi bond has a smaller bond enthalpy and is broken easier
- The Pi bond attracts electrophiles (as it is an electron dense region)
Define stereoisomerism
Same molecular and structural formula, different arrangement of atoms in space
Why can E/Z isomers form in alkanes
The C=C bond restricts rotation
What must a compound have to have E/Z isomers
- A C=C bond
- Two different groups attached to each carbon atom on the C=C bond
E isomer
Priority groups on opposite sides of the C=C bond
Z isomer
Priority groups on same side of the C=C bond
In electrophilic addition
which C will the HALIDE bond to in order to form the MAJOR product
The carbon bonded to the most other carbon atoms
Alkene to alkane
Hydrogenation - H2/Ni catalyst
Alkene to haloalkane
Electrophilic addition - X2 or HX
Alkene to alcohol
Dilute H3PO4