All Short Questions Flashcards
What are cathode rays?
streams of negatively charged particles called electrons
Bananas contain small quantities of potassium‐40, a radioactive isotope. What is the daughter nucleus when K‐40 emits an electron in beta decay?
40
Ca
20
State Avogadro’s law.
equal volumes of gases contain equal numbers of molecules under the same conditions of temperature and pressure
What is the oxidation number of sulfur in
(i) sulfur dioxide (SO2),
(ii) the sulfate ion (SO42–)?
i) + 4
ii) +6
Give two differences between a sigma and a pi covalent bond.
1) sigma covalent bond involves the head on overlap of orbitals while pi covalent bonds involves the sideways overlap over orbitals
2) sigma bonds are stronger that pi bonds as there is more of an overlap in sigma bonds than in pi bonds
In the electrolysis of aqueous KI with inert electrodes one half‐equation is:
2I– (aq) —> I2 (aq) + 2e–
Write a balanced half‐equation for the reaction that takes place at the negative electrode
during this electrolysis.
2H20 + 2e- —-> 2H2 + 20H-
Define bond energy.
it is the average energy needed to convert one mole of covalent bonds and to separate the neutral gaseous atoms completely from each other
The structure of ibuprofen is shown. Ibuprofen is the active ingredient in many fever and pain‐relief suspensions given to children. A single 5 cm3 dose, suitable for children aged 1 to 3 years, contains 4.86 × 10–4 moles of ibuprofen.
How many milligrams of ibuprofen are in this single dose?
13(12)+2(16)+18(1) 206 mass=moles x molar mass mass= 4.8x10-4 x 206 mass=.100116g x1000 mass= 100.116mg
Write a balanced equation for the reaction – between limestone and carbonic acid in rainwater – that gives rise to temporary hardness in the water.
H2CO3+ CACO3= CA(HCO3)2
Answer part A or part B.
A Why is nitrogen gas unreactive?
or
B Draw two repeating units of the polymer poly(propene).
A) it is inert due to the large amount of energy need to break the triple bond
What was the purpose of Millikan’s ‘oil drop’
experiments of 1908 to 1913?
used charged oil droplets to determine the size of the charge on the electron
State and give the reason for the trend in atomic radii across the second period
of the periodic table.
they are decreasing due to the increasing nuclear charge and no increase in the screening effect of inner shells
Write the electron configuration (s, p, etc) for an iron atom.
1s2 2s2 2p6 3s2 3p6
Give two reasons why real gases deviate from ideal behaviour at high pressures
and low temperatures.
1) molecules have attractive and repulsive forces
2) real gas molecules have intermolecular forces
3) real gas molecules have a volume
Identify in the following reaction the Brønsted‐Lowry acid and its conjugate base.
PO43– + HNO3 -> NO3– + HPO42–
HNO3 –> NO3-
ACID. > CONJUGATE BASE
During the Olympics in Rio de Janeiro in 2016 the water in some swimming and diving pools turned green. Sodium hypochlorite in the pools had reacted with hydrogen peroxide, added in error, and this allowed the rapid growth
of green algae. The reaction that occurred was:
NaOCl+H2O2 NaCl+H2O+O2
Use oxidation numbers to show whether chlorine was oxidised or reduced.
NAOCL \+1-2+1 NACL \+1-1 Reduced
Write a balanced equation, or give the half equations, for the displacement reaction that occurs between chlorine gas and an aqueous solution of sodium bromide.
Cl2 +2e– → 2Cl–
2Br– →Br2 +2e–
State and explain the effect of adding a little tetraethyllead to an equimolar mixture of methane and chlorine
exposed to weak sunlight.
the rate of reaction increases as tetrahedral lead acts as a catalyst
Epoxyethane is used to manufacture car antifreeze. It is composed of 54.5% carbon, 9.1% hydrogen and 36.4% oxygen by mass.
Find the empirical formula of epoxyethane.
- 4 9.1 36.4
- =4.54 1. =9.1 16. = 2.275
- 54 9.1 2.275
- 275 =2 2.275=4 2.275= 1
C12H4O
Explain the term biochemical oxygen demand.
It is the amount of dissolved oxygen in ppm consumed by biological action when a sample of water is kept at 20oc in the dark for 5 days
Answer part A or part B.
A Which of the following gases makes the greatest contribution to the greenhouse effect?
carbon dioxide
water vapour methane
Give the reason for your choice.
or
B Give an example of (i) a molecular crystal, (ii) a covalent macromolecular crystal.
A) water vapour
it is the most abundant in the air
Why did Mendeleev place tellurium before iodine in his periodic table of the elements?
Mendeleev ordered the element in order of increasing atomic weight but tellurium which was heavier was placed before iodine the lighter one in order to make them fall into groups of elements with similar properties.
Identify the main energy levels involved in the electron transition that gives rise to the first (red) line of the Balmer series in the emission spectrum of the hydrogen atom.
energy level 2-3
identify the atomic symbol X and the atomic number Z of the daughter nucleus in the following nuclear equation. 137 137 0
Cs→ X+ e
55. Z –1
137
Ba
56