Allostropoes Flashcards
(39 cards)
What are allotropes?
Different form of an element in the same physical state
eg.Oxygen and ozone
What are allotropes of carbon?
1)Diamond
2)Graphite
3)Fullerene
3)Graphene
How carbon are bonded in diamond?
one carbon atom is covalently bonded to other 4 carbon atoms.
What is the hybridization of diamond?
sp3 hybridization (4 electron domain)
Structure of carbon atom in diamond
one carbon atom is covalently bonded to other 4 carbon atoms in tetrahedral shape. (109.5 degree)
How carbon are bonded in graphite?
one carbon atom is covalently bonded to other 3 carbon atoms.
What is the hybridization of graphite?
sp2 hybridization (4 electron domain)
Structure of carbon atom in graphite
one carbon atom is covalently bonded to other 3 carbon atoms in trigonal planar shape.(120 degree)
Contains delocalized electrons because of the movement of electrons in pi bond of the double bonds.
Graphite bonds
One carbon atom is attached to other 3 carbon atoms.Therefore there must be a double bond in the structure of graphite.(Double bond=1 sigma bond & 1 pi bond)
The electrons in the pi bond are loosely attached and can move freely.
Structure of graphite
Each graphite exist as hexagon structure and arranged in layers by London dispersion force.
What are giant covalent molcules?
a molecule that contain regular repeated patteren that are covalently bonded
Among carbon allotrope,which are giant covalent molecule?
Diamond, Graphite & Graphene
Why fullerence is not giant covalent?
Bcus it contains both 6 carbon rings and 5 carbon rings not only one repeated unit.
How many carbon atoms are in fullerence?
60 carbons
Do fullerenes & Graphene can conduct electricity?
Yes
Both contains delocalized electrons (bcus of the double bonds)
What is graphene?
A single layer of graphite
Why diamond can’t conduct electricity?
Bcus there is no delocalized electrons in the diamon (bonded by single bonds)
The layers of graphite are fixed.True or False?
False
The layers can slide each other b/c they are held together by london dispersion force.
Shape of Fullerene
Sphere shape (12 pentagons & 20 hexagons)
Shape of graphene
Honeycomb shape
All of the carbon allotropes can conduct electricity.True or False?
False
Diamond cannot conduct electricity
All of the carbon allotropes are giant covalent structures.True or False?
False
Fullerene is not giant covalent.
All of the carbon allotropes can conduct heat.True or False?
True
Diamond is vvery efficient thermal conductor.
All of the carbon allotropes have very high melting point.True or False?
False
Fullerene have low melting point