Amount of Substance Flashcards

(40 cards)

1
Q

What is the definition of relative atomic mass?

A

The average mass of an atom of an element relative to 1/12th of the relative atomic mass of an atom of carbon-12

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2
Q

What is the definition of relative formula mass?

A

The average mass of that molecule compared to 1/12th of the relative atomic mass of carbon-12

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3
Q

What is avogrado’s constant?

A

6.022 × 10²³

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4
Q

What is the equation for moles using mass and Mr?

A

moles = mass / Mr

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5
Q

What is molar mass and what are the units?

A

1 mole of atoms, it is numerically the same as Mr. The units are g/mol or g mol^-1

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6
Q

How do you work out the number of molecules?

A

moles x avogadro’s constant

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7
Q

How do you work out the number of atoms?

A

moles x avogadro’s constant x number of atoms

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8
Q

What is the equation for % uncertainty?

A

instrument uncertainty / quantity measured x 100

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9
Q

How do you convert g/dm3 into mol/dm3

A

÷ Mr

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10
Q

What is the equation to find the dilution factor?

A

initial concentration / target concentration

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11
Q

What is the dilution factor?

A

The sum of parts

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12
Q

How do you find the volume of 1 part in the dilutions method?

A

volume of solution / dilution factor

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13
Q

What is the ideal gas equation?

A

PV=nRT

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14
Q

How do you convert Celsius into Kelvin?

A

+273

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15
Q

How do you convert Kelvin into Celsius?

A

-273

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16
Q

How do you convert kPa into Pa?

A

x 10^3

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17
Q

How do you convert mPa into Pa?

18
Q

How do you convert cm³ into m^3?

19
Q

How do you convert dm^3 into m^3?

20
Q

What are the two steps of finding the Mr of a gas?

A

Find the moles with the ideal gas equation of n=PV/RT
Find the Mr with the equation Mr=mass/mol

21
Q

What are the errors in calculating the Mr?

A

The volume of gas in a syringe is greater than the true volume because some air leaked into the syringe, so the Mr is too small.
The volume of the gas in the syringe is less than the true volume because not all the liquid is vaporised in the syringe, so the Mr is too large.

22
Q

What is the empirical formula?

A

It is the simplest (whole number) ratio of the number of atoms of each element present in a molecule

23
Q

What is the molecular formula?

A

It is the actual number of atoms of each element in one molecule of a compound.

24
Q

What are the steps to find the empirical formula?

A
  1. Write atoms in ratio
  2. Write percentages in ratio
  3. Divide by Ar
  4. Divide by smallest mol for a whole number ratio in simpliest form
25
What are spectator ions?
They are ions that are chemically unchanged at the end of a reaction
26
What are the rules for ionic equations?
1. Make sure the equation is balanced 2. Only write chemicals that are (aq) as ions (apart from elements) 3. Make sure both sides are balanced 4. Cancel any species that are identical either side of the arrow
27
What are the rules of predicting masses in chemical reactions?
1. Ensure you have a balanced equation 2. Calculate moles 3.Use ratios in the equation to get moles of the unknown 4. Convert back to mass
28
What is the yield of a chemical?
The amount of product formed
29
Why would the actual yield be much less than the theoretical yield?
Some of the products may be left in the container or the reaction may not go to completion (reversible) or the reactants are reversible
30
What is the equation for calculating percentage yield?
Percentage yield= Actual yield / theoretical yield x 100
31
What is the equation for atom economy?
Atom economy= Mass of desired product / total mass of reactants or products x 100 Or Mr
32
Is 100% atom economy possible?
Yes only if one product if formed
33
Describe the ,method for making up a standard solution?
- Weigh out the sample in weighing boat and transfer to beaker - Re - weigh the boat and calculate the mass added ( Weighing by difference) - Dissolve sample in distilled water and add into a volumetric flask with the washings of the glass rod, funnel and beaker - Make up to 250cm^3 in volumetric flask, near the 250 mark and use a pipette to ensure that the bottom of the meniscus is on the 250cm^3 mark - Invert to give a homogenous solution
34
What are the steps during a titration?
-Fill a burette with the acid of a known concentration after rinsing and ensure there no air bubbles. -Accurately measure an amount of the alkali using a calibrated pipette and pipette filler after rinsing. -Add the alkali to a conical flask with a few drops of a suitable indicator (phenolphatlein) -Run in the acid from the burette and swirl the flask until the colour just changes, showing that the solution in the conical flask is now neutral-This is a rough titre - Repeat the procedure until three values for the volume of acid used at neutralisation are the same, within experimental error. Concordant results are within 0.1cm^3 of each other.
35
Why do you rinse the conical flask near the end point?
To add reagents back to flask
36
Why do you wash the burette with water before titration?
To remove any soluble impurities
37
Why do you wash the burette with the solution that will be used?
To ensure that the concentration of the solution is not changed by water
38
How do you reduce error in a burette?
Use larger volumes of solutions by decreasing the concentration
39
How do you convert grams into tonnes?
x (1x10^6)
40
How do you convert cm^3 to litres?
/1000