Amount of Substance Flashcards

(44 cards)

1
Q

What is molecular formula?

A

Actual number of atoms of each element in a compound

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2
Q

What is empirical formula?

A

simplest whole number ratio of atoms of each element in a compound

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3
Q

What is the formula for atom economy

A

(mr of desired product/ mr of all reactants) x 100

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4
Q

what is the calculation for NUMBER of moles

A

number of molecules/ avogadro

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5
Q

What is %yield?

A

Tells us about the practical efficiency of the process

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6
Q

What is the formula for % yield?

A

(actual yield/mass/ theoretical mass) x 100

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7
Q

What is the formula for actual yield?

A

(percentage yield x theoretical yield) / 100

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8
Q

How do you carry out a %yield calculation

A
  1. work out moles of reactant
  2. use mole ratio from the balanced equation work out the theoretical moles of product
  3. using the theoretical moles of product calculate the theoretical maximum mass of product.
  4. use equation to work out %yield
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9
Q

What is the equation for %purity?

A

(actual mass/impure mass) x 100

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10
Q

How do you carry out a % purity calculation

A
  1. work out the moles of the product (reactant is impure)
  2. use mole ratio from the balanced equation work out the actual moles reactant that reacted
  3. use actual moles of reactant calculate its actual mass
  4. use equation to work out %purity
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11
Q

what is the formula for apparatus error?

A

(margin of error/quantity) x100

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12
Q

what is the ideal gas equation?

A

pv = nRt

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13
Q

How do you convert KPa to Pa

A

x 1000

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14
Q

How do you convert cm3 to m3

A

divide 1,000,000

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15
Q

How do you work out empirical formula

A
  • divide the percentage of the element by its Mr
  • Work out the ratio of all elements by dividing by the smallest number
  • Ratio should be whole numbers
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16
Q

How do you calculate molecular formula from empirical formula and molecular mass

A

Mr of molecule
————————— = multiplier
Empirical Mr

Multiply empirical values by multiplier

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17
Q

how can you calculate the limiting/excess reactant?

A
  • work out the moles of both reactants
  • reactant with the smallest value is limiting
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18
Q

how do you calculate the average titre

A

titres (volume) within 0.1 of eachother

subtract them then divide by 2

19
Q

what is a back titration?

A

A base is treated with an excess of acid on the leftover acid is titrated (vice versa)

You can then work back to find the original base that reacted

20
Q

How can you use the limiting reagent to work out the maximum mass of products that can be made?

A
  • after working out the limiting use the ratio to calculate moles of the product
  • use moles to calculate mass
21
Q

define atomic number

A

number of protons in an atom

22
Q

how do you convert mg to g

A

divide by 1000

23
Q

how do you convert t into kg

24
Q

What is the equation for density

25
What is the equation for concentration
moles/volume
26
how do you convert m3 to dm3
x 1000
27
how do you convert cm3 to dm3
divide 1000
28
How do you express concentration in g dm^-3
Conc (g dm-3) = Conc in (mol dm-3) x Mr
29
What are the stages of making a volumetric solution
Transfer known mass of solid Dissolve in water Transfer and wash
30
How do you transfer a known mass of solid
1. Place a weighing boat on the balance and tare. 2. Transfer the solid to the weighing boat. 3. Record the mass.
31
How do you dissolve solid in water to make volumetric solution
1. Transfer the solid into the beaker and rinse weighing boat with deionised water and transfer the washings to the beaker. 2. Add 100 cm3 of deionised water to the beaker. 3. Stir with a glass rod until the solid has dissolved.
32
How do you transfer and wash when making a volumetric solution
1. Transfer the solution to a volumetric flask using a funnel. 2. Rinse the beaker stirring rod and funnel with deionised water and transfer the washings to the volumetric flask 3. Add deionised water to the volumetric flask to make up to the graduation mark. Use a dropping pipette when close to the mark 4. Invert flask to make sure the solution is thoroughly mixed.
33
Why is a rough titration carried out first
used to determine the approximate amount of standard needed to neutralise an unknown solution.
34
How do you set up and carry out a titration
1. Rinse the burette with deionised then with standard solution 2. Fill the burette including the area below the tap with the standard solution 3. Take initial reading and record to 2 decimal places (ending in a 5 or 0.) 4. transfer solution to conical flask and add indicator 5. add the solution from the burette, with constant swirling of the conical flask, until the indicator just changes colour. (indicates neutralisation)
35
Why should you only add few drops of indicator
indicators are weak acids, and any more would affect the end point.
36
Why is a conical flask used?
so no solution spills when swirling.
37
Why should you remove the funnel before starting the titration
ensures no additional drops enter from the burette and lower your titre.
38
How do you calculate the concentration of the solution in the conical flask after a titration
1. use table to work out concordant results and work out the avg titre 2. use avg titre and conc of the standard solution (a) to workout moles of (a) 3. use ratio from balanced equation to calculate moles of solution in conical flask (b) 4. calculate concentration of (b) using worked out moles and given volume
39
How do you calculate the original mass and Mr from a titration
1. write balanced equation 2. the volume and concentration of HCl to calculate the moles of standard solution (a) 3. use the ratio from the balanced equation to deduce the moles solution in conical flask (b) 4. calculate the sample factor and calculate the number of moles in the original 250 cm3 solution 5. using these moles calculate the original mass of (b)
40
How to do calculate moles of an acid from a back titration
1) Work out the excess moles of acid in the titration equation 1 2) Work out the moles of NaOH base required to neutralise the left-over acid. (ratio from equation 2 will allow you to determine the left-over moles of acid) 3) Use ratio and moles of NaOH to calculate moles of left-over acid 4) Subtract your left-over moles from excess moles of acid to determine how many moles of acid actually reacted in equation 1 5) Use your ratio in equation 1 to work out the moles of your carbonate base. (not NaOH) 5) Use your carbonate moles to determine an answer
41
What colour is Phenolphthalein in an acid
Colourless
42
What colour is Phenolphthalein in an alkali
pink
43
What colour is Methyl orange in an acid
Red
44
What colour is Methyl orange in an alkali
Yellow