APES Unit 9 Flashcards
(44 cards)
cause of ocean acidification
incr. CO2 in atm. leads to incr. ocean CO2 through direct exchange.
CO combines with ocean water to form carbonic acid H2CO3
carbonic acid and dissociates formula
CO2 + H2O –> H2CO3 which can break into HCO3- , and H+ + CO32- (carbonate already in ocean) which forms HCO3-
how can ocean acidification damage marine organisms
they make shells using calcium (Ca+) and carbonate (CO3 2-). makes carbonate less available and causes marine shells to breakdown.
weaker shells
anthropogenic cause of ocean acidification
fossil fuel combustion
deforestation
coal/gas combustion
UV-C, UV-B UV-A radiation
UV-C is 100% absorbed by ozone in stratosphere. 90% of UV-B and 50% of UV-A
without ozone layer life
would be non-existant because radiation damages tissue and mutates DNA.
human health benefits of ozone layer
prevents skin cancer and cataracts
how ozone absorbs UV-B and UV-C
UV-C radiation breaks down O2 into O and O
– when O reacts with O2, O3 is formed
– UV-C and UV-B can reverse this process by breaking O3 into O2 and O
continued formation and breakdown of O3 in stratosphere absorbs all UV-C and much of UV-B radiation
anthropogenic ozone depletion
CFCs are primary anthropogenic cause of O3 breakdown
– UV radiation causes free chlorine atom to separate from CFCs
– chlorine atom bonds with one of O from O3 (ClO and O2)
– free O will steal O from ClO leaving Chlorine to go breakdown more O3
one chlorine atom can damage the whole ozone layer
one Cl atom can persist in atm. for 50 - 100 yrs. and can destroy upto 100,000 O3 atoms
natural ozone depletion
antarctic winter forms polar stratospheric clouds (PSC)
clouds made of ice crystals trap chlorine compounds
in antarctic spring, PSCs begin melting and release Cl compounds
what is main way to reduce anthropogenic O3 depletion
phasing out and replacing CFCs
montreal protocol
global agreement to phase CFCs our of production
what were CFCs replaced with
replaced with HCFCs, which still deplete O3 and are GHG but less
(not permanent solution but temporary transition option)
Replacement for HCFCs is HFCs, still GHG but not O3 depleting
current slow transition to HFOs, not GHG, not O3 depleting
CFC
chlorofluorocarbon
HCFC
hydro-chlorofluorocarbon
HCF
hydro-fluorocarbon
HFO
hydro-fluoroolefin
the greenhouse effect
(positive of greenhouse effect)
gases in earth’s atm. trap heat from the sun and radiate it back down to earth
+ without greenhouse effect, earth would be too cold to support life
major gasses and sources
CO2 - fossil fuel combustion, decomposition, deforestation
CH4 - nat. gas extraction and combustion, animal agr., anaerobic decomposition
N2O - agr. soils (denitrification of nitrate)
CFCs/HCFCs/HCFs - refrigerants, propellants in aerosol products
water vapor - evaporation and transpiration
water vapor as a GHG
technically GHG; does not contribute to global warming but can have a reinforcing effect
– stays in atm. for much shorter time, only about 9 days
GWP (global warming potential
measure of how much gasses can contribute to global warming over 100 yrs. relative to CO2
GWP depends on
1) residents time
2) infrared absorption (heat)
GWP of different GHGs
CO2 has 1 (since they are relative to CO2)
CH4 is 25-28 times more potent than CO2
N2O is 300
CFCs… is 1,600 - 13,000