Atomic and Molecular Structure Flashcards

1
Q

Dalton’s atomic theory explains that all matter is made up of -__ which are ___. And that all atoms of a given element are identical in __ and ___

A

atoms, indivisible, mass, property

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2
Q

___ electrons are all electrons except the valence electrons, and the number of electrons in each energy level is equal to ____

A

core, 2n^2

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3
Q

atoms of the same element that have the same number of protons but different number of neutrons

A

isotopes

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4
Q

involves changes to the physical properties of a substance; no new products are formed and no new chemical bonds are formed or destroyed

A

physical reactions

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5
Q

When bonds are formed or broken and new substances are made

A

chemical reaction

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6
Q

When two different compounds come together to form a single compound; usually release energy

A

synthesis

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7
Q

When a compound breaks down into two or more products; require energy

A

decomposition

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8
Q

When one element replaces another in a compound

A

single displacement

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9
Q

When two elements replace one another in a compound

A

double displacement

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10
Q

When a substance reacts with O2 to form light and heat

A

combustion

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11
Q

Bohr believed that electrons move in __ __ around the nucleus, but this has since been disproven

A

fixed orbitals

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12
Q

states that it is impossible to know both the exact location and momentum of an electron at the same time

A

heisenberg’s uncertainty principle

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13
Q

the space that is the most probable locations for electrons

A

electron cloud

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14
Q

The __ ___ ___ describes the energy level of the electron, and it must be ____. The maximum number of electrons each level can hold is given by ____. The ___ number on the periodic table represents the energy level of the valence electrons

A

principle quantum number, N>=1, 2n^2, row

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15
Q

the __ __ __ describes the orbital shape, and can be between __ and ___.

A

azimuthal quantum number, orbital shape, 0, n-1

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16
Q

When l = 0, the subshell is ___, which is ___ shaped, when l=1 the subshell is ___ which is ____ shaped, when l=2 the subshell is ____ which is ___ shaped and when l=3, the subshell is ___

A

s, spherical p, dumbell, d, clover, f

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17
Q

The magnetic quantum number describes the __ ___ in space, and takes the value of __ and ___

A

orbital orientation, -l, +l

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18
Q

The __ ___ __ describes the angular momentum of the electron and can be either __ or ___

A

spin quantum number, -1/2, +1/2

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19
Q

Says that no two electrons within an atom can have the exact same quantum numbers

A

pauli’s exclusion principle

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20
Q

The s orbital has __ electrons, the p orbital has ___ electrons, the d orbital has ___ electrons, and the f orbital has ___ electrons

A

2, 6, 10, 14

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21
Q

describes the number of electrons in each energy level and the order in which subshells are filled

A

electron configuration

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22
Q

In electron configuration notation, the first number describes the __ __ __, and the letter describes its ___, the superscript describes the number of ___ in it

A

principle energy level, subshell, electrons

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23
Q

the alkali and alkaline earth metals are the ___ block, the nonmetals are the ___, the transition metals are the __, and the lanthinide and actinides are the ___ block

A

s, p, d, f

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24
Q

says that subshells tend to get filled from lower energy to higher energy

A

aufbau principle

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25
Q

Says that all orbitals of a subshell are first singly occupied before they are doubly occupied

A

hund’s rule

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26
Q

Exceptions to the electron configurations occur when elements like to have ___ or ___ ___ subshells. This includes elements like __, __ and ___, ___, ___

A

full, half full, Cr, Mo, Au, Ag, Cu

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27
Q

Valence electrons are always removed first from the __ ____ subshell

A

highest energy

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28
Q

When two species that have the same electronic configurations

A

isoelectronic species

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29
Q

Ionic compounds are ___ __ that have high melting and __ ___, are soluble in ___, and __ __ in aqueous and __ forms

A

crystalline solids, boiling points, water, conduct electricity, molten

30
Q

Covalent compounds have weaker bonds than ionic, thus have lower _- and ___ points, are ___ or ___ at room temperature, are __ in water, and do not conduct ___

A

melting, boiling, liquid, gas, insoluble, electricity

31
Q

distance between the each atom in a covalent bond; decreases as the number of electron pairs shared increases

A

bond length

32
Q

The energy needed to break the covalent bond; increases as the electron pairs shared increases

A

bond energy

33
Q

distribution of charges

A

polarity

34
Q

When atoms of a chemical compound are covalently bonded in a network

A

covalent network solid

35
Q

Examples of covalent network solids are __ and ___

A

diamond, quartz

36
Q

When in a covalent bond, both electrons come from the same atom

A

coordinate covalent

37
Q

electrostatic attractive force between delocalized electrons and positively charged metal ions

A

metallic bond

38
Q

Metallic compounds like __ and __ fused together, conduct ___, are ___, ___, and ___

A

gold, silver, electricity, ductile, malleable, lustrous

39
Q

dipole dipole interactions does not occur in ____ because the molecules are too far apart.

A

gasses

40
Q

Ion dipole interactions are the attraction between the ____ and ___ molecules, and are stronger than dipole dipole interactions,

A

ions, polar

41
Q

Increasing the intermolecular forces increases the __ and __ points, the ___, the __ __, and decreases the __ ___

A

melting, boiling, viscosity, surface tension, vapor pressure

42
Q

The __ ___ rule applies to hydrogen, helium, ____, ____, ___ and -__

A

reduced octet, lithium beryllium, boron, aluminum

43
Q

___ ___ is when elements have more than 8 outer electrons and apply to elements within the __ row or more that have a __ subshell

A

exceeding octet, 3rd, d

44
Q

the central atom is the one that can make the most __, and is usually the __ ___ atom. It is also usually ___

A

bonds, least electronegative, carbon

45
Q

___ and ___ will never be the central atom, and will only form one bond.

A

hydrogen, halogens

46
Q

the formula for formal charge

A

number of valence electrons - non bonding electrons - number of bonds

47
Q

Bonding occurs when orbitals with electrons ___. When this happens, the atomic orbitals are ____ into shapes that resemble the atomic orbitals. This forms a __ ___. The number of orbitals must be ___. Hybrid orbitals have better __ and form ___ bonds

A

overlap, hybridized, covalent bond, conserved, overlap, stronger

48
Q

sigma bonds allow for __ __ about its axis, whereas ___ bonds do no

A

free rotation, pi

49
Q

All single bonds are ___ bonds. A double bond has ___ pi bond and a triple bond has ___ pi bonds

A

sigma, 1, 2

50
Q

the number of lone pairs or bond locations around an atom

A

number of lone pairs or bond locations around an atom

51
Q

Double and triple bonds only count as ___ electron domain

A

1

52
Q

The bond order is equal to

A

number of bonding orbital electron - number of antibonding orbital electron / 2

53
Q

bond order is equal to the number of ___

A

bonds

54
Q

an atom that has one or more unpaired electrons and thus is attracted to a magnetic field

A

paramagnetic

55
Q

when an element has no unpaired electrons and thus repels a magnetic field

A

diamagnetic

56
Q

As the bond order increases, the bond strength ____. An increase in ___ __ produces a decrease in bond strength. The greater the ____, the greater the bond strength. The presence of less ___ ___ indicates a greater bond strength

A

increase, atomic radii, polarity, lone pairs

57
Q

VSPER theory determines the __ __ of ___ molecules. Electron pairs ___ each other and will arrange themselves as far apart as possible

A

geometric arrangement, covalent, repel,

58
Q

has 2 electron domains and 180° separation

A

linear

59
Q

has 3 electron domains and 120° separation

A

trigonal planar

60
Q

has 4 electron domains and 109.5° separation

A

tetrahedral

61
Q

Has 5 electron domains with 90°, 180°, and 120° separations

A

trigonal bipyramidal

62
Q

Has 6 electron domains with 90° separation

A

octahedral

63
Q

a bent shape that occurs with ___ bonds and __ lone pair has a bond angle of ___ 120°

A

2, 1, <

64
Q

a trigonal pyramidal shape that occurs due to ___ bonds and __ lone pair has a bond angle of ___

A

3, 1, 107.5°

65
Q

The bent shape created by __ bonds and ___ lone pairs has a bond angle of ___

A

2, 2, 104.5°

66
Q

a ____ shape is formed with 4 bonds and 1 lone pair, with angles that are greater than __ and ___

A

seesaw, 90, 120

67
Q

A ____ shape results from 3 bonds and 2 lone pairs, and has a bond angle of ___90

A

t, <

68
Q

a ___shape can result from a molecule of 2 bonds and 3 lone pairs, and has a bond angle of ___

A

linear, 180°

69
Q

a ___ __ shape results from a molecule with 5 bonds and 1 lone pair and its bond angle is ____ 90

A

square pyramidal, <

70
Q

A __ __ shape results from a molecule with 4 bonds and 2 lone pairs and has a bond angle of ____

A

square planar, 90°