Atomic Structure Flashcards

1
Q

Who is the father of modern chemistry?

A

Antoine Lavoisier

  • Proposed the law of conservation of mass
  • Proposed combustion
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2
Q

Define “Law of Conservation of Mass”

A

Total mass of a substance present after a chemical reaction is the same as the total mass of substances before a reaction

total mass of reactants = total mass of products

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3
Q

Define “Law of Definite Proportions”

A

Proposed by Joseph Proust, this states that all samples have same proportions by mass of constituent elements regardless of source

This gave way to the identity of substances

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4
Q

Define “Law of Multiple Proportions”

A

Proposed by John Dalton, first empirical evidence on the existence of atoms. He managed this through the use of gases
We can observe the formula of two elements based on proportion

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5
Q

Development of the Atomic Model:

Who is Democritus?

A

“Atomos” - Proposed that matter is composed of indivisible particles called atoms

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6
Q

Development of the Atomic Model:

Who is John Dalton?

A

Proposed basic atomic theory

  • Each element is composed of atoms
  • Atoms of different elements are different from each other
  • atoms of one element cannot become another
  • atoms combine to form compounds
  • hard sphere model - this indivisible sphere is the smallest building block in the world
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7
Q

Development of the Atomic Model:

Who is JJ Thomson?

A
  • Discovered electrons by analysing cathode rays - cathode ray tube experiment
  • Measured mass/charge ratio for electrons
  • Proposed the plum pudding model of an atom (electrons are randomly arranged on a positively charged sphere)
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8
Q

Development of the Atomic Model:

Who is Robert Milikan?

A
  • Performed oil drop experiment to determine electron charge
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9
Q

Development of the Atomic Model:

Who is Ernest Rutherford?

A
  • conducted the gold foil experiment

- Discovered that the atom was mostly empty space with positively charged center called the nucleus

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10
Q

What are Isotopes?

A

Atoms of the same element (same # protons) but different # of neutrons thus a different mass

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11
Q

What are isotones?

A

Atoms with the same number of neutrons but different number of protons

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12
Q

What are Isobars?

A

Atoms with the same mass but different atomic number

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13
Q

There are 3 naturally occuring isotopes of Mg. Their masses and percent natural abundances are 23.985 amu, 78.99%; 24.986 amu, 10.00%; and 25.982 amu, 11.01%. Calculate weighted average atomic mass.

A

Average atomic mass = summation [(isotope mass) x (fractional abundance)]

24.305 amu

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14
Q

Define amplitude, wavelength, and frequency

A

Amplitude (A) - vertical distance from midline of wave to the peak or trough
Wavelength (lambda) - horizontal distance between identical points (peak or trough) on successive waves
Frequency (v) - number of waves that pass through a particular point in 1 second (Hz = 1 cycle/s)

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15
Q

What is EM Radiation?

A

Electromagnetic radiation is the speed of the wave that travels at the speed of light in a vacuum (c=lambda x v)

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16
Q

True or False: Increasing wavelength = decreasing frequency

A

True

17
Q

True or False: Increasing energy = Increasing frequency

A

True

18
Q

True or False: Max Planck proposed that energy is continuous

A

False. He proposed that energy is quantized (or in steps) through blackbody radiation

19
Q

What is the photoelectric effect?

A

Creation of electric current from exposure to light particles (photons)

Electrons are only ejected to form a current at a MINIMUM FREQUENCY of the wave

hv > Wo = no electrons ejected