Atomic structure Flashcards

atomic and ionic radius

1
Q

state the trend of atomic radius down a group and across a period

A

atomic radius decreases across a period and increases down the group

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2
Q

explain why atomic radius decreases across a period

A
  • atomic number increases therefore an increases positive nuclear charge
  • the larger the nuclear charge the greater the pull of the nuclei on on the electrons which results in a smaller atom
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3
Q

explian why atomic radius increases down the group

A
  • there is an increased number of shells down the group
  • the electrons in the inner shells repel the electrons in the outermost shell shielding them from the positive nuclear charge
  • it weakens the pull of nuclei on the atom resulting in larger atoms
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4
Q

define atomic radius

A

it is the measureof the size of an atom

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5
Q

atomic radius has to do with…

A

atomic radius has to do with size of the atom and pull of nuclei on electrons
a greater/stronger pull means a smaller atom which means decreasing atomic radius
a weaker pull means a larger atom which means increasing atomic radius

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6
Q

atomic radius is in/directly proportional to

A

-it is directly proportional to increase in number of shells

and indirectly proportional to increasig atmoic number/nuclear charge

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7
Q

why is there a sharp increase in atomic radius from period to period (noble gas to alkali metal)

A

theres a an added principal quantum shell which increases the shielding of the outer shell electrons and therefore atomic radius

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8
Q

define ionic radius`

A

measure of size of an ion

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9
Q

state the predictable patterns of ionic radius`

A

ionic radius increases with increasing negative charge

and decreases with increasing positive charge

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10
Q

what theory explains the patterns of ionic radius

A

the electron shell theory

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11
Q

explain the increase in ionic radius with reference to the electron shell theory

A

ions with negative charges are formed by atoms that accept electrons (nuclear charge remains the same). the outer most electros are further away from the positively charged nucleus and are therefore held weakly by the attractive forces increasing the ionic radius

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12
Q

eplain the decrease in ionic radius with reference to the electron shell theory

A

positively charged ions are formed by atoms that lose electrons (nuclear charge remains the same) however there are now fewer eectrons which undergo greater elctrostatic forces of attraction decreasing the ionic radius

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13
Q

define an isotope

A

an isotope is an atom of the same element that contains the same number of protons but different number of neutrons

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14
Q

why do isotopes have the same chemical energy

A

this due to isotopes having the same number of electrons in the outershells. electrons take part in chemical reactions and therefore determine the chemistry of an atom

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15
Q

why do isottopes have diferent physical properties

A

the difference between isotopes is the number of neutrons and since these are natural subatomic particles they add mass to the atom resulting in different physical properties such as small differences in their mass and density

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