atomic structure and periodic table Flashcards

(74 cards)

1
Q

the model of an atom consists of what?

A

a small nucleus and electrons in orbital

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2
Q

who found this current model ?

A

rutherford

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3
Q

how did rutherford find it

A

scattering experiment 1911

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4
Q

what does the nucleus consist of?

A

protons and neutrons

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5
Q

whats the charge of a nucleus

A

positive

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6
Q

what is the atomic mass

A

the number of protons and neutrons

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7
Q

how is the atomic mass represented

A

A

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8
Q

what is the atomic number

A

the number of protons

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9
Q

how is the atomic mass represented

A

z

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10
Q

what is an isotope

A

different atom of the same element, same atomic number but different Atomic mass

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11
Q

what is relative atomic mass

A

mass of an atom of an element relative to 1/12 t of the mean mass of C-12

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12
Q

what is relative isotopic mass

A

the isotopic mass of an isotope relative to 1/12 the mean mass of the C-12 isotope

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13
Q

what is relative molecular mass

A

mean mass of a molecule of a compound relative to 1/12 the mean mass of the C-12 isotope

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14
Q

what is relative formula mass

A

Mr but used for compounds with giant structures

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15
Q

how are ions formed

A

when an atom gains or looses an electron

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16
Q

what are they used for

A

the analytical technique of mass spectrometry

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17
Q

what is time of flight

A

time of flight records the time it takes for ions of each isotope to reach a detector

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18
Q

what is step 1 of mass spectrometry

A

ionisation

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19
Q

how is step 1 of mass spectrometry done

A

atom in gaseous state is bombarded with electrons

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20
Q

what is step 2 of mass spectrometry

A

acceleration

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21
Q

how is step 2 of mass spectrometry done

A

positively charged ions are accelerated to a negative detector

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22
Q

what is step 3 of mass spectrometry

A

ion drift

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23
Q

how is step 3 done

A

ions are deflected by a magnetic field into a curved path

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24
Q

what is step 4 of mass spectrometry

A

detection

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25
how is step 4 of mass spectrometry done
+ ions git the - detection plate. they gain an electron, producing a current. the greater the abundance, the greater the current produced
26
what is step 5 of mass spectrometry
analysis
27
how is step 5 of mass spectrometry done
current values are used in a combination with the flight times
28
how can u calculate the Ar using printed spectra
Ar-(m/z x abundance)/ total abundance
29
what is ionisation energy
the minimum energy required to remove the highest energy electron from an atom in its gaseous state
30
what is successive ionisation energies
when further electrons are removed- usually requires more energy because as electrons are removed, the electrostatic forces increase between the nucleus and electrons
31
trend in 1st ionisation across a period
increases as the radius decreases due to more electrons and more electrostatic forces
32
trend in 1st ionisation down a group
decreases as there are more shells that act as shielding and therefore there are less electrostatic forces
33
what does a sudden large increase in successive ionisation energies on a graph indicate
a change in energy levels
34
why is the first ionisation energy of aluminium lower than expected?
it has a single pair of electrons with opposite spin. this means there is a repulsion
35
what is the current model of electronic configuration based on
- emmission spectra provides evidence for quantum shells - successive ionisation energies prove quantum shells within atoms and sugest the atoms group - first ionisation energy
36
what are electron orbitals
a cloud of negative charge where electrons are held
37
what are the different types of electron orbitals
S P D & F
38
what is the shape os the S orbital
spherical
39
what is the shape of the P orbital
dumbbell
40
what do the electron orbitals corrispond with
blocks in the periodic table
41
what periods fall in the S block
periods 1&2
42
what periods fall in the D block
Transition metals
43
what periods fall in the P block
3,4,5,6,7&8
44
what periods fall in the F block
the two at the bottom
45
how many electrons can the S subshell hold
2 electrons
46
how many electrons can the P subshell hold
6 electrons
47
how many electrons can the D subshell hold
10 electrons
48
what is the energy trend of the orbitals from S-D
the energy of the orbitals increase which means that the orbitals are filled from S-D
49
whats the order of the orbitals being filled
S P D F
50
sodium has 11 electrons . how will the configuration be written
Na=1s2, 2s2, 2p6,3s1
51
how many energy levels does sodium have
3
52
how many orbitals does sodium have?
4
53
what is spin in an electron
within an orbital, electrons pair up with opposite spin
54
why do electrons pair up with opposite spin?
so the atom has maximum stability
55
how is spin represented
opposite arrows
56
rule one for writing out electron configurations
the lowest energy orbital is filled first
57
rule two for writing out electron configuration
electrons with the same spin fill up an orbital first before pairing begins
58
what is rule 3 for electron configuration
no single orbital holds more than 2 electrons
59
what is an exception to the rule?
if electron spins are unpaired and therefore unbalanced, it produces a natural repulsion between the electrons
60
what does a natural repulsion within the electrons result in
a very unstable atom
61
what happens when the atom is unstable
the electrons may take a different arrangement to improve stability
62
the 3p4 orbital has a single pair of electrons with opposite spins making it unstable, what then happens
an electron moves to the 4s shell to make it more stable and the configuration is now 3p3 4s1
63
what does periodicity refer to
the study of patterns of physical atomic and chemical properties
64
what does the periodic table arrange the elements by
the atomic (proton) number
65
what do the elements along a period have in common
they have the same number of shells
66
what do elements down a group have in common?
they have the same umber of electrons in its outer shell
67
what happens to the atomic radius across a period and why
decreases because there are more electrons which means there is a higher nuclear charge and more inter molecular forces
68
what happens to atomic radius down a group and why
increases because there are more shells
69
ionisation energy along a period
increases because of the decreased atomic radius which results in higher attractions
70
ionisation energy down a group
decreases because of more shells which act as sheilds and higher atomic radius
71
where do the melting points of period 2 element peak
around the middle
72
boron and carbon form what?
giant covalent lattices with strong covalent bonds
73
what bonding does lithium and beryllium have?
metallic bonding
74
what is the general trend in ionisation energies along period 2
it increases because the atomic radius is decreasing