Atomic Structure and The Periodic Table Flashcards

1
Q

What is an atom?

A

The smallest part of an element that can exist.

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2
Q

What is a compound?

A

They contain two or more elements that are chemically combined.

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3
Q

What is a mixture?

A

Two or more elements or compounds not chemically combined.

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4
Q

What are the five methods of separating mixtures?

A

Filtration, crystallisation, simple distillation, fractional distillation and chromatography.

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5
Q

How is the atoms structured?

A

It has electrons in the outer shell surrounding the nucleus; containing neutrons and protons.

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6
Q

What is the ‘plum pudding’ model of the atom?

A

The atom is a ball of positive charge with negative electrons embedded in it.

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7
Q
  1. What was John Dalton’s interpretation of the atom (1803)?
A

He used an Ancient Greek idea of atoms being indivisible, those of a given element are identical, and compounds are combinations of different types of atoms.

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8
Q

What was correct about John Dalton’s concept of the atom?

A

He recognised atoms of a particular element differ from other elements.

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9
Q

What was incorrect about John Dalton’s concept of the atom?

A

Atoms aren’t indivisible. They’re composed from subatomic particles.

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10
Q
  1. What was J.J. Thomson’s interpretation of the atom (1904)?
A

He discovered electrons in atoms in 1897, for which he won a Nobel Prize, and produced the ‘plum pudding’ model of the atom.

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11
Q

What was correct about J.J. Thomson’s interpretation of the atom?

A

He recognised electrons as components of atoms.

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12
Q

What was incorrect about J.J. Thomson’s interpretation of the atom?

A

Atoms have a nucleus.

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13
Q
  1. What was Ernest Rutherford’s interpretation of the atom (1911)?
A

He fired positively charged alpha particles at a thin sheet of gold foil. Most passed through with little deflection, but some deflected at large angles. This was only possible if the atom was mostly empty space, with the positive charge concentrated in the centre: the nucleus.

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14
Q

What was correct about Ernest Rutherford’s interpretation of the atom?

A

He realised that positive charge was localised in the nucleus of an atom.

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15
Q

What was incorrect about Ernest Rutherford’s interpretation of the atom?

A

It did not explain why electrons remain in orbit around the nucleus.

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16
Q
  1. What was Niels Bohr’s interpretation of the atom (1913)?
A

He modified Rutherford’s model of the atom by stating electrons move around the nucleus in orbits of fixed sizes and energies. Electron energy in this model was quantised.

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17
Q

What was correct about Niels Bohr’s interpretation of the atom?

A

Proposed stable electron orbits; explained the emission spectra of some elements.

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18
Q

What was incorrect about Niels Bohr’s interpretation of the atom?

A

Moving electrons should emit energy and collapse into the nucleus; the model did not work well for heavier atoms.

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19
Q

What experiment led to the new model of the atom by Ernest Rutherford?

A

The alpha particles scattering experiment.

20
Q

What is the alpha particles scattering experiment?

A

Ernest Rutherford fired alpha particles at a thin gold foil and unexpectedly observed some particles were deflected at large angles, even bouncing back created as flashes on the fluorescent screen, leading to the discovery of the atomic nucleus.

21
Q

What is filtration?

A

It is used to separate an insoluble solid from a liquid or solution by passing the mixture through filter paper, allowing the liquid (the filtrate) to pass through while retaining the solid as residue.

22
Q

What is evaporation?

A

It is used to isolate a dissolved solid (solute) from a liquid (solvent) by heating the solution, allowing the solvent to evaporate, and leaving the solid residue behind.

23
Q

What is distillation?

A

It uses evaporation and condensation to separate a liquid from a solution or to separate different liquids based on their boiling points.

24
Q

What is chromatography?

A

It is used to separate different substances dissolved in a liquid with different solubilities.

25
What is the relative size of an atom?
They have a radius of about 0.1nm or 1×10¹⁰ metres.
26
What are isotopes?
Atoms of the same element with the same number of protons but different numbers of neutrons, resulting in different atomic masses.
27
What are the three subatomic particles?
A proton, a neutron and an electron.
28
What are the vertical columns of a periodic table called?
Groups.
29
Why are atoms in the same group similar?
They have the same number of electrons in their outer shell/orbit.
30
Who is responsible for the modern periodic table?
Dimitri Mendeleev.
31
How did the periodic table develop?
Before the discovery of protons, neutrons and electrons, scientists attempted to classify the elements by arranging them in order of atomic weights, not mass. Mendeleev overcame some of the problems by leaving gaps for elements he thought had not been discovered and, in some places, changed the order based on atomic weights. Elements with properties predicted by Mendeleev were discovered and filled the gaps. Knowledge of isotopes made it possible to explain why the order based on atomic weights was not always correct.
32
What is an ion?
An atom with a positive or negative charge due to a gain or loss of (an) electron(s).
33
What ion do metal atoms form?
Positively charged ions.
34
What are Group 0 elements?
Noble gases; they are unreactive and do not easily form molecules.
35
How do atoms become ions?
By gaining or losing electrons in ionic bonding.
36
What is the trend shown by Group 1 elements?
Reactivity increases down the group.
37
Why do alkali metals (Group 1 elements) become more reactive as you go down the group?
Outer electrons are further from the nucleus, meaning there is a weaker electrostatic force, meaning it can be lost more easily.
38
How do Group 1 elements react with oxygen and water?
They oxidised quickly are are very malleable. They explode in contact with water.
39
How does Lithium react with water?
It floats with gentle fizzing and hydrogen gas release. It gradually dissolves to give a colourless solution (LiOH). The final solution has pH12-14.
40
How does Sodium react with water?
It floats with igorous fizzing and hydrogen gas release. It melts and rapidly dissolves to give a colourless solution (NaOH). The final solution has pH14.
41
How does Potassium react with water?
It floats with very vigorous fizzing and hydrogen gas release, which bursts into a lilac flame, and it very rapidly dissolves to give a colourless solution (KOH). The final solution has pH14.
42
How does Rubidium react with water?
It sinks and explosively releases hydrogen gas and instantaneously dissolves to give a colourless solution (RbOH). The final solution has pH14.
43
What is the trend shown in group 7 elements?
The reactivity decreases down the group.
44
Why do halogens (Group 7 elements) become less reactive the further down the group?
The outer electrons are further from the nucleus, meaning there are weaker electrostatic forces between the nucleus and the incoming electron, which is gained less readily.
45
What is displacement in a reaction?
When a more reactive element takes the place of a less reactive element in a compound.