atomic structure/electrons Flashcards

(30 cards)

1
Q

democritus

A

atomos: undivided

could not be divided, created, or destroyed

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2
Q

aristotle

A

four elements: fire, water, air, and earth

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3
Q

lavoisir

A

father of modern chemistry
law of conservation of mass
33 elements

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4
Q

proust

A

law of definite proportions

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5
Q

john dalton

A

law of multiple proportions: the mass ratio for elements can be expressed in small, whole numbers
first table elements by mass
dalton’s atomic theory

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6
Q

daltons atomic theory

A
  1. all matter is made up of atoms
  2. all atoms of a given element are identical in mass and properties
  3. compounds are formed by a combination of two or more atoms
  4. a chemical reaction is a rearrangement of atoms
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7
Q

j.j. thomson

A

cathode ray experiment in 1897: electrons have negative charge, charge to mass ratio, and both + and - particles are present
plum pudding model in 1909

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8
Q

robert millikan

A

“oil drop experiment” in 1908

used to calculate mass of electron

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9
Q

ernest rutherford

A

gold foil experiment in 1911

nuclear atomic model in 1910: the nucleus is dense and mostly empty space

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10
Q

niels bohr

A

modern model of the atom: dense nucleus surrounded by orbiting electrons

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11
Q

erwin shrodinger

A

proposes wave mechanical model of electron

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12
Q

james chadwick

A

nobel peace prize for discovering neutron

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13
Q

max planck (and equation)

A

said energy is quantized and can only be absorbed in small whole number multiplies related to frequency
e=hv defines one quantum/photon of energy

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14
Q

einstein

A

emr is a stream of photons (little packets of energy) with mass and energy

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15
Q

de broglie

A

emr has wave and particle characteristics

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16
Q

bohr

A

calculated the wavelength of a photon emitted by hydrogen electron

17
Q

electromagnetic

A

waves of electric and magnetic fields at right angles to each other

18
Q

radiation

A

menergy that travels and spreads as it goes out (radiates out from charged particles)

19
Q

electromagnetic radiation spectrum

A

radio waves, microwaves, infrared, ultraviolet radiation, x-rays, and gamma rays

20
Q

heisenberg uncertainty principle

A

impossible to know the exact location and momentum of an electron at the same time so it ruled out define locations for electrons

21
Q

wavelength

A

distance between any point on a wave and the corresponding point on the next wave

22
Q

frequency

A

how many wavelengths pass a fixed point in a given time

23
Q

speed of propagation

A

(c) rate at which wave travels through space

as frequency increases, wavelength decreases

24
Q

photoelectric effect

A

einstein

metals emit electrons when struck by light

25
particle vs wave
particle is localized and wave is delocalized | particle is matter and wave is energy
26
wave-particle daulity
light can show wave or particle behavior
27
atomic emission spectra
each element has a unique emission spectra
28
rydberg formula for hydrogen
full spectrum of emission from hydrogen
29
bhor atomic theory and its flaws
introduced quantum concept into atomic theory predicted emission spectrum of hydrogen only worked for hydrogen and other one-electron systems
30
quantum mechanical model
behavior of the electron described by a set of allowed wave functions (Ψ) called orbitals each wave function has definite energy electron moves between orbitals by absorbing/emitting quantum of energy equal to the energy difference between the states (similar to bohr model).