Basic concepts of Organic Chemistry Flashcards
(24 cards)
How do you name organic compounds?
- Find the longest carbon chain of the molecules
- The functional group tells us the ending of the molecule
- Number the carbon chain so that the functional group sit on the lowest possible carbon number
- Make a not of the carbon attached to the functional group and place the number before the suffix
- Any side chains and less important functional groups are written as prefixes
- If there is more than 1 identical functional group, put di, tri or tetra
Define general formula
An algebraic formula that can describe any member of a homologous series of compounds
Define structural formula
The arrangement of atoms in a molecule without showing all the bonds
Define empirical formula
The simplest whole number ratio of atoms of each element in a compound
Define molecular formula
The actual number of atoms in an element
Define displayed formula
Shows the arrangement of atoms showing all the bonds and atoms in the molecule
Define skeletal formula
Shows the bonds of the carbon skeleton only (functional group are only shown)
Define Homologous series
A family of organic compounds that have the same general formula and similar chemical properties
What are the homologous series?
- Alkanes
- Alkenes
- Alcohols
- Aldehydes
- Ketons
- Carboxylic Acid
- Haloalkanes
- Cycloalkanes
- Esters
Define functional group
The group of atoms that is responsible for the characteristic reactions of a compound
Define an alkyl group
A hydrocarbon fragment with general formula CnH2n+1
Define an aliphatic compound
A compound containing carbon and hydrogen joined together in straight chains, branched chains or non-aromatic rings
Define an alicyclic compound
An organic compound that contains carbon and hydrogen joined together in an non-aromatic ring
Define an aromatic compound
An organic compound that contains a benzene ring
Define an unsaturated hydrocarbon
A hydrocarbon with carbon-carbon double bonds
Define a saturated hydrocarbon
A hydrocarbon with single carbon-carbon bonds
Define structural isomers
Compounds with the same molecular formula but different structural formula
Define chain isomers
Compounds with the same molecular formula but different arrangement of carbon skeleton
Define positional isomers
Compounds with the same molecular formula but different position of the functional group on the carbon skeleton
Define functional group isomers
Compounds with the same molecular formula but different functional group
Define homolytic fission
- The bond breaks evenly and each atom receives one electron from the bonded pair
- Two uncharged radicals are formed
Define heterolytic fission
- The bond breaks unevenly with one of the bonded atoms receives both electrons from the bonded pair
What is a radical?
- Radicals are very reactive and have an unpaired electron
What do we use to show the movement of electrons?
- Curly arrows