Basic Principles Flashcards

1
Q

Who proposed that a vital force was responsible for the formation of organic compounds

A

Berzilius

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2
Q

Who rejected berzilius Vital force in eightteen twenty eight

A

F wohler

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3
Q

What did f wohler synthesize

A

Organic compound urea From an inorganic compound ammonium cyanate

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4
Q

What’s the formula of urea

A

Nh2conh2

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5
Q

So synthesized acetic acid and methane by inorganic sources

A

Berthelot

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6
Q

Order of strength of bond
Big to small

A

Sp
Sp2
Sp3

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7
Q

Order of length of bond
Big to small

A

Sp3
Sp2
Sp

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8
Q

Order of electronegativity
Big to small

A

Sp
Sp2
Sp3

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9
Q

Methane formula

A

Ch4

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10
Q

Ethene formula

A

C2h4

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11
Q

Ethyne formula

A

C2h2

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12
Q

What’s pi bond

A

Parallel orientation of two p orbitals

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13
Q

Plane of molecule is ___ to p orbitals in a pi-pi overlap

A

Perpendicular

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14
Q

What is the valency of nitrogen

A

3.

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15
Q

Name the hybridisation for the Bonds
Single
Double
Triple

A

Sp3 sp2 sp respectively

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16
Q

Hypnotization of carbon and ch3cl

A

Sp3

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17
Q

What is v s e p r theory

A

The repulsion between the pears of valence electrons

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18
Q

Arrange them in the order of Highest repulsion to lowest repulsion
Bond pair bond pair
Lone pair bond pair
Lone pair Lone pair

A

Lone pair lone pair
Lone pair bond Pair
Bond pair bond pair

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19
Q

Shape of ab2

A

Linear

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20
Q

Shape and angle of ab3

A

Trigonal planar 120

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21
Q

Shape and angle of ab2L

A

Bent or v shape 120

22
Q

Shape and angle of ab4

A

Tetrahedral 108°23’

23
Q

Shape and angle of ab3L

A

Pyramidal less than 109.5 nearly 107

24
Q

Shape and angle in ab2l2

A

Bent or v 109.5

25
Angle and shape in ab5
120 trigonal bipyramidal
26
Angle and bond in ab4L
Seesaw 180
27
Angle and bond in ab3l2
T 90
28
Angle and bond in ab2l3
180 linear
29
angle and bond in ab6
90 octahedral
30
Angle and shape in ab5l
Square pyramidal 90
31
Angle and shape in ab4l2
Square planar 90
32
Angle and shape in ab7
Pentagonal bipyramidal 90
33
Geometry - hybridisation Linear Trigonal planar Tetrahedral Trigonal bipyramidal Octahedral
Sp Sp2 Sp3 Sp3d Sp3d2
34
tell the formulas of Methane Ethane propane butane pentane hexane heptane Octane nonane decane icosane triacontane
ch4 C2H6 c3h8 C4h10 c5h12 C6h14 C7h16 c8h18 C9h20 c10H22 C20h42 c30h62
35
Where do we use the prefix iso
We use it when a methyl group located on the second carbon of a carbon chain.
36
Where do we use neo
When all but two carbon forms a continuous chain
37
Where do we use secondary With exceptional case
Secondary is used when the functional group is bonded to a secondary carbon.This can be used Only for the chain containing four or more carbons
38
Name the order of decreasing priority of functional groups
sulfonic acid carboxylic acid anhydride Ester acid halide amide cyanide isocyanide aldehyde Ketone alcohol thio alcohol amine ester epoxide azo nitro alkane alkene alkane halide
39
What is chain isomerism
Same molecular formula different structure
40
What are position isomers
Different position of functional group
41
What is functional group isomerism
Same molecular formula but different functional groups
42
What is metamerism
Same molecular formula but different alkyl groups
43
What is stereoisomerism
Same sequence of covalent bombs but different in positions of their atom or groups
44
What's a carbocation
Sextet of electrons and positive charge
45
Ch3+ ion is known as
Methyl cation or methyl carbonium ion
46
When are carbocations are classified into primary secondary and tertiary
When one two or three carbons are directly attached to positively charged carbon
47
Stability of carbocations big to small
Tertiary Secondary Primary
48
Shape of carbocationh
Trigonal planar
49
Order of stability of alkyl radicals Small to big
Free radical Primary Secondary Tertiary
50
What's a nucleophile
Reagent that brings electron to reactive side
51
Whats an electrophile
Reagent that takes electron from reactive side
52
What is polarizability effect
Temporary electron displacement effects are seen in a molecule when a reagent approaches to attack it