Bonding Flashcards

(35 cards)

1
Q

What creates the ionic lattice?

A

The ions attracting oppositely charged ions in all directions

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2
Q

What state are most ionic compounds at room temperature?

A

-Solid

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3
Q

Why do ionic compounds have high melting points?

A

-strong electrostatic forces of attraction between ions

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4
Q

Why do ionic lattices with greater charges have greater melting points?

A

There are stronger forces of attraction between ions

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5
Q

What do most ionic compounds dissolve in?

A

Polar solvents

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6
Q

How does an ionic compound dissolve in water?

A

The polar water molecules break down the lattice by isolating the ions

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7
Q

Why are lattices with grater ionic charge generally less soluble?

A

There is a stronger electrostatic attraction between particles

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8
Q

What is the formula for an ammonium ion?

A

NH4+

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9
Q

What is the formula for a nitrate ion?

A

NO3-

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10
Q

What is the formulae for a sulfate ion?

A

SO42-

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11
Q

What is the formula for a phosphate ion?

A

PO43-

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12
Q

What is covalent bonding?

A

The strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms

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13
Q

How does a covalent bond take place?

A

The overlap of atomic orbitals (one in each orbital to form a pair)

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14
Q

Why are covalent bonds “localised”?

A

The bond is purely between atoms

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15
Q

How many single covalent bonds does boron tend to make?

A

3

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16
Q

Despite it’s outer electrons being n=3, how many covalent bonds can phosphorus make? What is this called?

A

5 - expansion of the octet

17
Q

What is another word for a dative bond?

A

A coordinate bond

18
Q

What is a dative bond?

A

When the shared pair of electrons has been supplied by one of the bonding atoms only

19
Q

What is a dative bond shown by?

20
Q

What is average bond enthalpy a measurement of?

A

Covalent bond strength

21
Q

What does a greater bond enthalpy value indicate?

A

A stronger covalent bond

22
Q

Why does H3O have a 1+ charge?

A

A pair of electrons is provided by the oxygen atom as it pairs with a H+ ion

23
Q

How are ionic compounds formed?

A

When 2 oppositely charged ions attract and are held together by electrostatic forces

24
Q

What are 3 properties of ionic compounds?

A

1) High MP and BPs
2) Can’t conduct electricity when solid
3) When molten or aqueous can conduct electricity

25
Why can ionic compounds conduct electricity when molten or aqueous?
The ions are mobile and can move to opposite terminals and carry charge
26
How are the ions in a lattice isolated by the polar water molecules?
The ions are attracted to slight charges on the polar molecule
27
Why can a sodium ion form more than one ionic bond even though it only has one outer electron?
Each ions is attracted to all nearby ions
28
Why do lone pairs repel more strongly than bonded pairs?
They are held closer to the central atom
29
What is the electron pair repulsion theory used for?
To predict and explain the shapes of molecules
30
Why do larger ions have a weaker attraction to the oppositely charged ion?
They have a greater ionic radius, so attractive forces have to act over a greater distance.
31
Why are ionic substances often brittle?
The layers of alternating chargers are distorted when force is applied, so like charges repel, breaking apart the lattice into fragments.
32
In a covalent bond dot and cross diagram, are the electrons on the lines or inbetween?
Doesn’t matter but should do it in between
33
Why are shorter covalent bonds stronger ?
Atoms are held closer together so the forces of attraction are greater and require more energy to overcome
34
Are double and triple bonds shorter than single covalent bonds?
Yes so they are stronger
35
Why is a dative bond treated as a standard covalent bond once it has formed?
It reacts exactly the same way and has the same properties regarding length and strength