Bonding Flashcards

(29 cards)

1
Q

2 bonds, 0 lone pairs

A

Linear, 180

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2
Q

3 bonds, 0 lone pair

A

trigonal planar, 120

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3
Q

2 bonds, 1 lone pair

A

Bent or Angular <120

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4
Q

4 bond pairs, 0 lone pairs

A

Tetrahedral, 109.5

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5
Q

3 bond pairs, 1 lone pair

A

Trigonal pyramid, <109

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6
Q

2 bond pairs, 2 lone pairs

A

Bent or angular «109

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7
Q

5 bonds, 0 lone pairs

A

trigonal bipyramidal, 90, 120

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8
Q

4 Bond Pairs, 1 Lone Pair

A

Seesaw 90, 120

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9
Q

3 bond pairs, 2 lone pairs

A

T-shaped, 90

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10
Q

2 bond pairs, 3 lone pairs

A

Linear, 180

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11
Q

6 Bond Pairs, 0 Lone Pairs

A

Octahedral, 90

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12
Q

5 bond pairs, 1 lone pair

A

square pyramidal, <90

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13
Q

4 bond pairs, 2 lone pairs

A

square planar, 90

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14
Q

3 bond pairs, 3 lone pairs

A

T-shaped, 90

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15
Q

2 bond pairs, 4 lone pairs

A

Linear 180

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16
Q

Give one reason why ice is less dense than water

A

Water molecules are held further apart than in liquid water

17
Q

Coordinate bonding

A

Shared pair of electron from..

18
Q

Explain how the lone pairs of electrons on the oxygen atom influences the bond angle on oxygen difluoride

A

Lone pairs repel more than bond pairs, bond angle will be lower

19
Q

Explain how permanent dipole-dipole forces arise between hydrogen chloride molecules.

A
  1. Differences in electronegativity leads to bond polarity
  2. Attractions between δ+ on one molecule and δ- on another molecule
20
Q

Chlorine has a lower boiling point because the forces between the molecules are weak.

Explain how these forces arise between chlorine molecules.

A
  • Random movement of electrons in one molecule creates temporary dipole (creates an imbalance in electron density)
  • induces a dipole in neighbouring molecules
  • these temporary dipoles attract temporary attraction between δ+ and δ-
21
Q

Ammonium chloride

A

Covalent bond
Dative covalent bond
Ionic bond

22
Q

Describe the structure and bonding in magnesium (2)

A
  1. Giant lattice of mg2+ cations
  2. Electrostatic attractions between cations and delocalised electrons
23
Q

Ionic bonding

A

The electrostatic attraction between oppositely charged ions formed by electron transfer

24
Q

Covalent bond

A

Share a pair of electrons

25
Metallic bonding
Is the electrostatic attraction between the positive ions and the delocalised electrons
26
Electronegativity
Relative tendency of an atom in a Covalent bond in a molecule to attract a bonding pair of electrons
27
Metals Explain why ... has a higher melting point than ...
1. Mention proximity of electrons (+ & -) 2. Strength of metallic bonding
28
Describe the structure and bonding in graphite and explain why the melting point of graphite is very high.
1. *Layers* of carbon atoms 2. Connected by covalent bonds 3. VDW forces between layers 4. Many strong covalent bonds need to be broken
29
Non metals Explain why ... has a higher bp than ...
1. Size of molecule 2. intermolecular forces