Bonding Flashcards

(39 cards)

1
Q

Cations

A

Positive ions

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2
Q

Anions

A

Negative ions

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3
Q

Ionic bond

A

Electrostatic force of attraction between positive and negative ion

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4
Q

Coordination number

A

Number of ions bonded

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5
Q

NaCl structure and coordination number

A

Cubic lattice structure

6:6 coordination

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6
Q

Covalent bond

A

Pair of electrons of opposite spins shared between 2 atoms

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7
Q

Coordinate bond

A

Covalent bond where both electrons come from one of the atoms involved

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8
Q

Example of electron deficient and why

A

BCl3 as boron’s outer electron not full

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9
Q

Electronegativity

A

A measure of the ability of an atom in a covalent bond to attract an electron bonding pair

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10
Q

Greater the “pull” (electronegativity)….

A

Greater sharing of electrons, slight negative charge

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11
Q

Electronegativity increases across period

A

Increasing number of protons, no change in shielding, greater pull on electrons

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12
Q

Weaker “pull” (electronegativity)…

A

Lesser share of electrons, slight positive charge

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13
Q

Electronegativity decreases down group

A

Because outer shell electrons further from pull of nucleus, greater shielding affect (more shells)

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14
Q

Electron density distribution in covalent bond

A

Equal sharing

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15
Q

Electron density distribution in polar covalent bond

A

Inequal sharing

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16
Q

Most ionic bond=biggest difference in…

A

Electronegativity

17
Q

VSEPR

A

Electrons negatively charged, repel each other, valence shell electrons pair up into orbitals, move to point of minimum repulsion

18
Q

2 bonding pairs

19
Q

3 bonding pairs

A

Trigonal Planar

120

20
Q

4 bonding pairs

A

Tetrahedral

109.5

21
Q

3 bonding pairs and 1 lone pair

A

Trigonal Pyramidal

107

22
Q

2 bonding pairs and 2 lone pairs

A

Non linear/bond

104.5

23
Q

5 bonding pairs

A

Trigonal Bipyramidal

90 and 120

24
Q

6 bonding pairs

A

Octahedral

90

25
Repulsion between lone pair and bonding pair is greater than...
Repulsion between 2 bonding pairs
26
Covalent bonds within a molecule..
Intramolecular forces
27
Covalent compounds have.... Between molecules
Intermolecular forces
28
Intermolecular forces weaker than...
Intramolecular forces
29
Intermolecular forces determine...
Physical properties (boiling point, solubility, volatility)
30
Van der Waals forces= | And how they exist
Dipole-dipole force | Exist between molecules with a permanent overall dipole
31
Why no overall dipole in Cl2?
Same electronegativity
32
Intermolecular forces get stronger as...
Size of molecule increases so boiling point increases, more electrons going down group
33
Instantaneous dipole
Electrons move quickly, likely that more electrons are on one side of molecule than other
34
Nearby atom/molecule electrons repelled by negative end of dipole creating a ....
Induced dipole
35
2 induced dipoles attract
Induced dipole-induced dipole | Van der Waals
36
Hydrogen bonds
Force between molecules containing hydrogen covalent let bonded to highly electronegative atoms (e.g.F,O,N)
37
Water is a...
Polar solvent, forms hydrogen bonds
38
Covalent compounds are... In water Because?
Soluble Dissolve as they can form similar strength intermolecular forces with water (e.g hydrogen bond)
39
Strongest to weakest bonds
Covalent > hydrogen > dipole-dipole > induced dipole-induced dipole