Bonding Flashcards
(39 cards)
Cations
Positive ions
Anions
Negative ions
Ionic bond
Electrostatic force of attraction between positive and negative ion
Coordination number
Number of ions bonded
NaCl structure and coordination number
Cubic lattice structure
6:6 coordination
Covalent bond
Pair of electrons of opposite spins shared between 2 atoms
Coordinate bond
Covalent bond where both electrons come from one of the atoms involved
Example of electron deficient and why
BCl3 as boron’s outer electron not full
Electronegativity
A measure of the ability of an atom in a covalent bond to attract an electron bonding pair
Greater the “pull” (electronegativity)….
Greater sharing of electrons, slight negative charge
Electronegativity increases across period
Increasing number of protons, no change in shielding, greater pull on electrons
Weaker “pull” (electronegativity)…
Lesser share of electrons, slight positive charge
Electronegativity decreases down group
Because outer shell electrons further from pull of nucleus, greater shielding affect (more shells)
Electron density distribution in covalent bond
Equal sharing
Electron density distribution in polar covalent bond
Inequal sharing
Most ionic bond=biggest difference in…
Electronegativity
VSEPR
Electrons negatively charged, repel each other, valence shell electrons pair up into orbitals, move to point of minimum repulsion
2 bonding pairs
Linear
180
3 bonding pairs
Trigonal Planar
120
4 bonding pairs
Tetrahedral
109.5
3 bonding pairs and 1 lone pair
Trigonal Pyramidal
107
2 bonding pairs and 2 lone pairs
Non linear/bond
104.5
5 bonding pairs
Trigonal Bipyramidal
90 and 120
6 bonding pairs
Octahedral
90