Bonding Flashcards

1
Q

Ionice Bonding

A

strong electrostatic forces between oppositely charged ions

loss or gain or electrons

3D giant ionic lattice

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2
Q

Melting and Boiling poitns in ionic

A

very high

very strong electrostatic forces to break

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3
Q

Condutivity of Ionics

A

solids do not conduct but they do when they are molten or in solution as the ions are free to move

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4
Q

Covalent Bonding

A

sharing a pair of electrons

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5
Q

Co ordinate bond

A

formed between lone pairs of electrons and a H+ ion

both electron come from the same atom

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6
Q

2 types of covalent bonds

A

macro molecular

simple molecular

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7
Q

Macro Molecular mp and bp

A

very high as alot of energy is needed to break the string covalent bonds

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8
Q

simple molecular mp and bp

A

very low as you do not break the strong covalent bonds themselves but you break the weak intermolecular forces between them which does not require a lot of energy

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9
Q

Metalic Bonding

A

cations in a sea of delocalised electrons

metal atoms detached from their outer electrons

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10
Q

Conductivity of metals

A

very good conductors on either state as the energy is carried by the delocalised electrons

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11
Q

Malleable

A

can be beaten into shape easily without having to be broken

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12
Q

Sliding

A

layers of cations ‘slide’ over each other while still bonded by the elcetrons
sliding can occur in all dimensions

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13
Q

Down the Metal Group melting point

A

decreases
same number of delocalised electrons but cation gets larger
less attraction to so easily lost

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14
Q

Across a Metal Period melting point

A

increases
number of delocalised electrons increases
charge increases
stroner attraction so harder to remove

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15
Q

Across Metal Period conductivity

A

increases
more delcoalised electrons
more charge to carry energy

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16
Q

Polar Covalent Bond

A

occurs when electron pairs are shared unevenly

due to electronegativity

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17
Q

Electron pull in PCB

A

towards the more electronegativity

away from the less electronegativ atom

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18
Q

Partial Charge

A

Delta Positive

Delta Negative

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19
Q

Dipole

A

molecule which is still neutral but contains partial charge that cancel out each other

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20
Q

Dipole Dipole

A

stronger attrcation between neighboruing molecules which also contain partial charges

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21
Q

Melting and Boiling Point of PCB

A

higher than expected

22
Q

Solubility in Water of PCB

A

Increased solubility

23
Q

Elcetronegativity

A

Ability of an atom to attract a pair of electrons in a covalent bond

24
Q

increases

A

across periods

25
decreases
up groups
26
Nuclear Charge
more protons | stronger attraction between nucleus and bodning pair of electrons
27
Aromic Radius
closer to the nucleus | stronger attraction between nucleus and bonding pair of electrons
28
Shielding
less shells of electrons between the nucleus and the electrons less shielding (less repulsion) stronger attraction between nucleus and bonding pair of electrons
29
Down a group Electronegativity
decreases atomic radius increases more shielding less attraction between nucleus and bonding pair of electrons
30
Across a period Electronegativity
increases atomic radius decreases more nuclear charge stronger attraction between nucleus and bonding pair of electrons
31
No Difference in Electronegativity
non polar covalent bond
32
<0.5 electronegativity
covalent bond
33
0.5<1.7 electronegativity
polar covalent bond
34
>1.7 electronegativity
ionic bond
35
both electrongeativites <1.5
metalic bonding
36
Intermolecular Forces
weak electrostatic forces of attraction between neighbouring molecules
37
3 types of intermolecular forces
Hydrogen Bonding Dipole-Dipole forces Van de Walls forces
38
Hydrogen Bonding
only between Flourine, Oxygen, Nitrogen deshielding the Hydrogen making it slightly positive (delta positive) attarction betweena lone pair on NOF and a deshielded hydrogen
39
In Liquids Hydrogen Bonds
are continuosly breaking and reforming
40
In Solids Hydrogen Bonds
are permanent
41
In Gases Hydrogen Bonds
are completly broken
42
As Electronegativity decreases Hydrogen Bond Strength
decreases
43
Dipole Dipole Forces
uneven electron disribution | differences in electronegativity
44
Permanet dipole causes
a permenant dipole in a neighbouring molecule
45
Van De Waal Forces
weakest intermolecular force atoms donate elctrons to the cloud leading to a momentary tempory dipole
46
when do Van De Waals occur
only happen when the other 2 intermolecular forces are not present can occur when there is dipole dipole but they are disregarded
47
VDW get stronger
as the number of electrons in the molecule increases
48
Boiling Points of Noble Gases down the group
Increase | as electron shells are added
49
starigh chain molecules
stronger van de waals forces | molecules can get closer
50
branched chain molecules
weaker van de walls forces | molecules are less close