bonding, structure and the properties of matter Flashcards

1
Q

ionic bonding

A

metal + non-metal
- metal atoms lose electrons to become positively charged ions
- non-metal atoms gain electrons to become negatively charged ions

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2
Q

describe an giant ionic structure

A
  • lattice consisting of a regular arragemnt of alternating charged ion
  • ions held together by strong electrostatic forces
    -^ high melting and boiling points
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3
Q

covalent bonding

A

non-metal + non-metal sharing eletrons to gain full outer shells

covalent bonds are very strong

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4
Q

why are simple covalent molecules weak

A

weak intermolecular forces inbetween each molecule

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5
Q

molecule vs compound

A

compounds- different elements!!!

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6
Q

what are large covalently bonded molecules?

A

polymers

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7
Q

name 3 giant covalent structures

A
  • graphite
  • diamond
  • silicon dioxide
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8
Q

2 advantages and 2 disadvantages of dot and cross diagrams

A

advantages:
- useful for illustrating share of electrons
- indicates which atom the bonding electrons come from
|
disadvantages
- fails t illustrate 3d arragement of atoms and electron shells
- doesnt inidicate relatives sizes of atoms

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9
Q

2 advantages and 2 disadvantages of ball and stick model

A

advantages
- useful for illustrating arragemnt of atoms in 3D space
- especially useful for visualising shape of molecule
|
disadvantes
- fails to indicate movement of electrons
- distance from atoms not accurate

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10
Q

2 advantages and 2 disadvantages of 2d representations of molecules

A

advantages
- 2d representations that are simpler versions of ball and stick model
- shows what atoms in molecule and how they are connected
|
disadvantages
- fails to show relative size of atoms and bonds
- doesnt represent the shape and how it looks 3d

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11
Q

metallic bonding- describe it in a metal

A
  • regular arragement of positive ions
  • delocalised electrons lost from ions shared across structure
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12
Q

at what point do freezing and condesning take place?

A

freezing- metling point
condensing- boiling point

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13
Q

what is particle theory?

A

can help explain that the amount of energy needed to change state from a solid to liquid and liquid to gas depends on the strength of forces between the particles of the substance

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14
Q

the stronger the force betweeen the particles of a substance…

A

the higher the energy required fro melting and boiling

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15
Q

limitations of particle theory

A

particles are represented by solid inelastic spheres that have no forces inbetween them

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16
Q

properties of ionic compounds

2

A
  • high melting and boiling points- giant structures and strong electrostatic forces iof attraction between ions
  • when molten or dissolved in water- can conduct electricity- ions free to move
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17
Q

properties of small molecules

A
  • substances consisting of small molecules have low m b points
  • weak intermolecular forces but strong covalent
  • intermolecular forces increase with size of molecules
  • dont conduct electricty because they dont have an overall charge
18
Q

what are polymers made from and how are they bonded both in atoms and units

A

monomers bonded by covalent bonds
atoms in polymer molecules bonded by covalent

19
Q

properties of metal
(bonding)

A
  • high m b points- strong electrostatic forces between ions and electrons
  • malleable- layers of positive ions slide over each other when force is applid
20
Q

what is an alloy?

A

mixture of two or more metals or metal witjh a non-metal like carbon

21
Q

alloys compared to pure metals

A
  • they are harder and stronger
  • resitant to corrosion or extreme temperatures
22
Q

why are alloys harder than pure metals?

A

contains different sized atoms that make it difficult for layers of atoms to slide over each other

23
Q

how do metals concuct electricty?

A

delocalised electrons carry charge THROUGH electron

24
Q

describe the structure of diamond

A
  • carbon atoms bonded to 4 other carbons
  • no intermoleculr forces
25
properties of diamond
- do **not** conduct **electricity**-** no free moving partices **to carry charge - very **high meltinng** point- strong **covalent** bonds between each carbon - very **hard** and **dense**- strong covalent bonded to 4 carbons
26
allotropes of carbon
- diamond - graphite - graphene - fullerene
27
describe structure of graphite
- carbon atom covalently bonded to 3 other carbons - 1 delocalised electron for each carbon - layers of hexagons attracted by weak intermolecular forces
28
properties of graphite
- conduct electricity- deloalised electron able to carry charge through structure - high melting point- strong covalent - slippery- lyayers can slide over each other due to weak intermolecular forces- means can be used as pencil or lubricant
29
describe structure of graphene
- single layer of graphite- sheet of carbon atoms covalently bonded - delocalised electrons
30
properties of graphene
- strong but light- strong covalent bonds unbroken - good conductor- delocalised electrons - flexible- the covalent bonds can bend without breaking - transparent- absorbs some light
31
structure of fullerenes and what are they
- either hollow tubes or spheres - based onhexagonal rings BUT can be 5 or seven - nanoparticles
32
first fullerene to be discovered
buckminsterfullerene - hollow sphere - 60 carbon atoms bonded
32
uses of fullerenes
- targeted drug delivery- can trap molecules - trapping catalyst molecules onto surfaces- big surface area
33
carbon nanotube
graphene rolled into cylinder high lenth to diameter ratios
34
why are nanotubes useful and what are they used in?
- resistant to breaking or stretching - conduct electricty - composites - electronics - nanotechnology - specialised materials
35
diameters of coarse, fine and nano particles and what ar coarse particles referred to as?
coarse- 2500-10000 nm fine- 100-2500 nm nano-1-100 nm dust
36
what happens to tthe surface area to vol ratio if side of cube decreased by 10?
increase by 10
37
why are nanoparticles different to the bulk chemical its made from?
- high surface area to volume ratio whic means smaller amounts are reuqired for it to be as effectibe | high sa- biger area for reactions
38
uses of nanoparticles and why
- catalysts- high sa:v - cosmetics- suncream & deodrants as leave no white marks - medicien and drug deliveries- more easily absorbed & can deliiver drugs to target areas more effectively - small electrical circuits - conduct electricty
39
disadvantages of nanoparticles
- in early stages so still unkown factors and potential risks - lack of understanding how they affect health - long term side effects potentially - small amount of toxicity in nanoparticle would be multiplied beaccuse of high sa:v -