Bonds & Details Flashcards

(39 cards)

0
Q

Covalent bond

When the electrons are not shared equally, it is called?

A

Electrons shared between 2 atoms

The bond is considered polar

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1
Q

Ionic bond?

Why does the bond stay together?

A

Electrons are taken and given away, resulting in charged particles.
Bond stays together due to electrical attraction

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2
Q

Covalent bonds result in what shapes?

Ionic bonds?

A

Covalent- VSEPR shapes

Ionic- crystals

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3
Q

Are acids an ionic or covalent bond?

What does the hydrogen act like?

A

Ionic

Like a cation

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4
Q

Cation vs anion

A

Cation- the positively charged ion

Anion- the negatively charged ion

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5
Q

What do covalent bonds form, while ionic bonds do not?

A

Molecules

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6
Q

Valence electron

A

An electron in the outermost energy level of an atom that can participate in bonding

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7
Q

Unshared pair (lone pair)

A

A nonbonding pair of electrons in the valence shell of an atom.

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8
Q

Single bond

A

A bond in which two atoms share one pair of electrons

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9
Q

Triple bond

A

Covalent bond in which 2 atoms share 3 pairs of electrons

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10
Q

Double bond

A

Covalent bond in which 2 atoms share 2 pairs of electrons

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11
Q

Resonance structure

A

Possible Lewis structure of a molecule for which more than one Lewis structure an be written

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12
Q

Lewis structure

A

A structure in which atomic symbols represent nuclei and inner-shell electrons and in which dots are used to represent valence electrons

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13
Q

What does VSEPR theory predict?

A

The 3-D formation of a molecule, shape of the molecule

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14
Q

The shape of molecules that contain only 2 atoms is

A

linear

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15
Q

Why is there not resonance structures of CO despite its triple bond?

A

There is no other way of making a different structure

16
Q

Electronegativity

A

Tendency of an atom in a molecule to attract shared electrons to itself

How good an atom is at attracting electrons to its nucleus

17
Q

Is “polar ionic” possible? Why or why not

A

No, Because in order to be polar, the en has to be less than 2 and greater than .5. If a bond is ionic, it will have an electronegativity greater than 2 meaning that it will never be polar.

18
Q

When should you use electronegativity to calculate whether or not a bond is polar?

A

When it is a covalent bond

19
Q

What does VSEPR stand for?

A

valence shell electron pair repulsion

20
Q

Why are nonpolar covalent bonds not common?

A

Because one atom usually attracts electrons more strongly than the other

21
Q

Nonpolar covalent bond

A

Attraction between two atoms in which bonding electrons are shared equally between the atoms

22
Q

Polar covalent bond

A

Attraction between two atoms in which bonding electrons are localized on the more electronegative atom

23
Q

Where on the periodic table is electronegativity the highest?

A

Upper right hand side

24
Where on the periodic table is electronegativity the lowest?
Bottom left hand side
25
Dipole molecule
One that has a partial positive charge at one end and a partial negative charge at the opposite end
26
In general, if the difference in electronegativity between 2 atoms is between 0 & .4 the bond formed is...
Non polar covalent
27
If the difference in electronegativity between 2 atoms is between .4 and 2 the bond formed is...
Polar covalent
28
If the electronegativity difference between 2 atoms is greater than 2 the bond formed is...
Ionic
29
If one atom has more electronegativity, then it is partially ____
Negative
30
The positive atoms shown in dipole moment arrows go where?
Towards the partially negative atom because it has more electronegativity
31
What is meant by unequal sharing of electrons in a polar bond?
More electronegative atoms pull on shared electrons more than the other atom so the charge is not evenly distributed -> opposite sides -> opposite charges
32
If their are lone pairs on the center element of the covalent bond, is it a polar or nonpolar molecule?
Polar
33
No lone pairs. Polar or nonpolar molecule?
Nonpolar
34
If dipole moments cancel out, is the molecule polar or nonpolar?
Nonpolar
35
If the dipole moments don't cancel & there are lone pairs, the molecule is...
Polar
36
Right on the periodic table, what happens?
Nucleus gets bigger so it's easier to steal electrons (more en)
37
Down on the periodic table, what happens?
Further away from the nucleus, more energy levels (less en)
38
Molecules have a certain ____ based on how the electrons repel each other
Shape