C10: Organic reactions Flashcards

1
Q

Describe the combustion of alkenes

A

Complete - Same as alkanes - produce carbon dioxide and water
Incomplete - more likely to take place with alkenes, produces unburnt carbon and therefore they are more likely to undergo incomplete combustion

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2
Q

What does the burning of alkenes look like?

A

Smoky flame

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3
Q

What is hydrogenation and what conditions does it require?

A

An alkene reacting with hydrogen,
Requires high temp and a nickel catalyst

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4
Q

What happens during the hydrogenation of an alkene?

A

An alkane is produced

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5
Q

Why do alkenes react similarly?

A

They are in the same homologous series - they have the same functional group

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6
Q

What is hydration and what conditions does it require?

A

The reaction between an alkene and water
- requires high temp (300C) and pressure (70atm) and phosphoric acid catalyst, water MUST be in steam
it is reversible

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7
Q

What is produced after the hydration of an alkene?

A

An alcohol

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8
Q

What happens when an alkene reacts with a halogen?

A

It forms a colourless solution and a dibromoalkane

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9
Q

What is the general formula for alcohols?

A

CnH2n+1OH

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10
Q

What are alcohols used in?

A

Fuels
Solvents
Drinks

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11
Q

What is the functional group of alcohols?

A

-OH

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12
Q

What are 2 ways to make ethanol?

A

Fermentation of yeast (no oxygen, 30C)
Hydration of ethene

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13
Q

Evaluate the 2 ways to make ethanol

A

Fermentation - renewable (sugar from plants), low temp (little energy \, aqueous solution of ethanol, requires purification
Hydration - very high yield // high temp (lots of energy = lots of money), ethene required is non-renewable

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14
Q

What is the solubility of alcohols in water like?

A

Soluble, form neutral solutions
As the number of carbon atoms increases, solubility decreases

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15
Q

What happens when alcohols react with sodium?

A

Produce sodium salt and hydrogen
Bubbles being produced

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16
Q

What happens when alcohols react with oxidising agents?

A

Produce a carboxylic acid and water

17
Q

What happens when alcohols combust completely?

A

Produce carbon dioxide and water

18
Q

What is the general formula of carboxylic acids?

A

CnH2n+1COOH

19
Q

What is the functional group of carboxylic acids?

A

-COOH

20
Q

What happens when dissolving carboxylic acids in water?

A

Form weak acids (partially dissociate) to form a negative ion (e.g. ethanoate) and a positive hydrogen ion (H+) (all aq). Have a HIGHER pH

21
Q

What is formed when carboxylic acids react with metal carbonates?

A

Form salt, carbon dioxide and water

22
Q

What is produced when carboxylic acids react with alcohols?

A

Ester + water

23
Q

What are some uses of esters?

A

Perfumes, fruity smells and solvents

24
Q

What is the one ester you have to remember?

A

Ethyl ethanoate

25
Q

What conditions does the reaction between a carboxylic acid and an alcohol require?

A

Sulfuric acid catalyst