C10 Organic reactions Flashcards

(34 cards)

1
Q

what is the functional group of alkenes?

A

the double covalent bond between two carbon atoms

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2
Q

what is the general formula for alkenes?

A

CnH2n

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3
Q

why is there no methene?

A

there has to be two carbon atoms for the carbon-carbon double bond

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4
Q

what does ‘functional group’ mean?

A

the part of the molecule which determines how it reacts

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5
Q

what is a homologous series?

A

a group of molecules which all have the same functional group and react in a similar way

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6
Q

what is produced during the combustion of alkenes?

A

carbon dioxide, water and unburnt carbon particles due to incomplete combustion

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7
Q

what does it look like when alkenes burn in air?

A

they burn with a smoky flame

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8
Q

what is hydrogenation?

A

when an alkene reacts with hydrogen

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9
Q

what are the conditions for the hydrogenation of alkenes?

A

150 degrees C, nickel catalyst

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10
Q

what happens during the hydrogenation of alkenes?

A

the hydrogen atoms add across the double bond to form an alkane

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11
Q

what is the reaction of water and an alkene called?

A

hydration

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12
Q

what happens during hydration of alkenes?

A

an alcohol is produced

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13
Q

what are the conditions for the hydration of alkenes?

A

water must be steam
temperature must be around 300 degrees C
pressure must be 70 atmospheres
phosphoric acid is used as a catalyst

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14
Q

what is a key fact about the hydration of alkenes?

A

the reaction is reversible

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15
Q

how is the yield of an alcohol increased during the hydration of alkenes?

A

unreacted alkene and steam are passed back through the catalyst

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16
Q

what happens when alkenes react with halogens?

A

the two halogen atoms add across the double bond and the double c-c bond forms a single c-c bond

17
Q

how is an alcohol formed?

A

remove an -H from an alkane
add an -OH to the alkane

18
Q

what is the functional group of alcohols?

19
Q

what are the first 4 alcohols?

A

methanol
ethanol
propanol
butanol

20
Q

what is the functional group of carboxylic acids?

21
Q

how do you form an ester?

A

replace the H in the -COOH of a carboxylic acid and add a hydrocarbon (alkyl) group

22
Q

what is the functional group of esters?

23
Q

what is fermentation?

A

the reaction in which the enzymes in yeast turn glucose into ethanol and carbon dioxide

24
Q

what does the use of ethanol as a fuel show?

A

alcohols are flammable

25
how do alcohols burn?
with a 'clean' blue flame
26
what is produced in the combustion of alcohols?
carbon dioxide water
27
how do alcohols react with sodium?
similar to water but less vigorous effervescence (bubbling) hydrogen gas is produced
28
how can alcohols be oxidised (not with combustion)?
using chemical oxidising agents
29
how can ethanol be oxidised to ethanoic acid?
chemical oxidising agents microbes in the air
30
what are the reactions of carboxylic acids like?
typical of acids (MASH, BASHCO2, CASHCO2 ect.)
31
why are carboxylic acids weak acids?
their molecules do not completely ionise when dissolved in water, most of the molecules stay as they are
32
what is the general formula for making esters?
carboxylic acid + alcohol --acid catalyst--> ester + water
33
what are the properties of esters?
distinctive smells (many are sweet and fruity) volatile
34
what are esters used for?
perfumes and food flavourings