C2.6 - the transition metals Flashcards

(33 cards)

1
Q

differences between transition metals and group 1

A
  • Compared to group 1 elements, transition metals have different physical properties.
    For example transition metals have a higher melting point and are more dense.
  • The exception is mercury which is a liquid at room temperature.
  • Transition metals also have different physical properties to group 1. They are much
    less reactive and do not react vigorously with oxygen or water.
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2
Q

where are the transition metals on the periodic table

A

The central block (between group 2 and 3) of the Periodic Table is known as the
transition metals.

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3
Q

how are flame tests carried out?

A
  1. Dip metal loop in dilute HCl, hold in Bunsen burner flame (blue flame), until no
    colour is seen.
  2. Dip the loop into the sample you are testing
  3. Place this into the flame and observe the colour
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4
Q

flame test for sodium

A

Sodium (Na+) = Yellow

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5
Q

flame test for lithium

A

Lithium Li+ = Crimson

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6
Q

flame test for potassium

A

Potassium K+ = Purple

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7
Q

flame test for copper

A

Copper Cu2+ = Green

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8
Q

flame test for calcium

A

Calcium Ca2+ = Red/Orange

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9
Q

what is the test for insoluble metal hydroxides

A

drops of sodium hydroxide are added to a solution of the metal hydroxide a precipitate may form.

Transition metal hydroxides are usually coloured

Main group elements normally form a white precipitate.

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10
Q

metal hydroxide test for aluminium ionic equation

A

Al3++ 3OH- -> Al(OH)

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11
Q

metal hydroxide test for magnesium ionic equation

A

Mg2++ 2OH- -> Mg(OH)2

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12
Q

metal hydroxide test for calcium ionic equation

A

Ca2++ 2OH- -> Ca(OH)2

calcium + hydroxide = calcium hydroxide

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13
Q

metal hydroxide test for Iron(II) ionic equation

A

Fe2++ 2OH- -> Fe(OH)2

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14
Q

metal hydroxide test for Iron(IIl) ionic equation

A

Fe3++ 3OH- -> Fe(OH)3

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15
Q

metal hydroxide test for copper ionic equation

A

Cu2++ 2OH- -> Cu(OH)2

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16
Q

what is the test for halides

A

Add 5 drops of dilute nitric
acid and 5 drops of silver nitrate

The colour of the
silver halide precipitate
formed will vary depend on
the halogen

17
Q

what colour is the halide: chloride

18
Q

what colour is the halide: bromide

19
Q

what colour is the halide: iodide

20
Q

what is the test for the negative ion, carbonate (CO3 2-)

A
  1. Add metal carbonate to dilute
    acid in a boiling tube.
  2. Connect
    the boiling tube to a test tube
    containing limewater.
21
Q

what is the positive result for carbonate (CO3 2-)

A

If the
limewater turns cloudy then a
carbonate ion is present

K2CO3+2HCl -> 2KCl+CO2+H2O

22
Q

what is the test for the negative ion sulphate (SO4 2-?

A
  1. Add 5 drops of dilute hydrochloric acid (HCl)
  2. Then add 5 drops of barium chloride.
23
Q

what is the positive result for sulfate?

A

If sulphate
ions are present then a white
precipitate will be formed.
Ba2++ SO42–>BaSO4
(This is the ionic equation
for the reaction. )

24
Q

what is the test for halides (chloride, bromide, iodide)

A

Add 5 drops of dilute nitric
acid and 5 drops of silver
nitrate

25
what is the positive result for chloride
white precipitate
26
what is the positive result for bromide
cream precipitate
27
what is the positive result for iodide
yellow precipitate
28
metal hydroxide test positive result for magnesium, Mg 2+
white precipitate, insoluble in excess
29
positive result for metal hydroxide test for calcium, Ca 2+
white precipitate, insoluble in excess
30
positive result for metal hydroxide test for Iron(II), Fe 2+
dirty green precipitate
31
positive result for metal hydroxide test for Iron(III), Fe3+
brown precipitate
32
positive result for metal hydroxide test for copper, Cu 2+
blue precipitate
33
positive result for metal hydroxide test for aluminum, Al 3+
White initially. In excess NaOH it dissolves to form a colourless solution.