C3 Flashcards

(46 cards)

1
Q

What are the formulae of these ions?

- Ammonium, ammonia, hydroxide, nitrate, carbonate, sulfate, silver

A
Ammonium - NH 4 (1+)
Hydroxide - OH (1-)
Nitrate - NO3 (1-) 
Carbonate - CO3 (2-) 
Sulfate - SO4 (2-)
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2
Q

What is the law of conservation of mass?

A

Atoms cannot be created or destroyed by a chemical reaction.

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3
Q

Reasons for mass increase in a chemical reaction?

A

If mass goes up, one of the reactants that is a gas may be oxygen (or any other gas), that gas will be counted in the reactants and increase the mass.

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4
Q

Reasons for mass decrease in a chemical reaction?

A

If the gas is open to the outside air/atmosphere, and not in a closed system, some products may leave as gases, reducing the mass.

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5
Q

Symbol equation and 2 half equations for sodium reacting with chlorine.

A

2Na(s) + Cl2(g) > 2NaCl(s)
Na > Na(1+) + e-
Cl2 + 2e- > Cl2(2-)

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6
Q

How do you write an ionic equation?

A

Break up the ions, aqueous’s, then cancel out the common things on each side of the equation. E.g.
CuSO4(aq) + 2NaOH(aq) → Na2SO4(aq) + Cu(OH)2(s)
Cu2+(aq) + 2OH–(aq) → Cu(OH)2(s)

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7
Q

What is a mole?

A

Amount of any substance that contains the same number of entities as there are atoms in 12.0g of carbon-12.

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8
Q

How many entities are there in one mole?

A

Avogadro constant. 6.022×10^23/mol.

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9
Q

How do you measure a mole of a substance.

A

Mass of 1 mol = its molar mass.

E.g. CO2 = 44g

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10
Q

Formula for finding mass of a substance using its mass and amount.

A

moles = mass/molar mass

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11
Q

What is the effect of a limiting reactant?

A

One reactant will be in excess, one will be limiting. The limiting reactant is used up and determines the amount of product formed.

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12
Q

Mole calculation method.

A

1) Balance the equation
2) Calculate RfM of what you want and RfM of the substance of which you know the mass.
3) See the ratio between the reactant and the product through their balancing numbers.
4) Use moles = mass/molar mass to find the desired mass.

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13
Q

How do you calculate stoichiometry (balancing numbers) of an equation?

A

1) Calculate the moles of each substance in the equation (moles = mass/molar mass)
2) Divide the moles in each substance by each of the lowest number of moles.
3) All the numbers will be whole numbers and those are the balancing numbers.

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14
Q

Define an endothermic reaction. Examples

A

An endothermic reaction takes in energy from the surroundings and is shown by a fall in temperature. Examples, neutralization and combustion.

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15
Q

Define an exothermic reaction.

A

An exothermic reaction gives out energy to the surroundings and is shown by a rise in temperature.

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16
Q

In an endothermic reaction, what will the reaction profile show?

A

The energy of reactants will be lower than the energy of the products. With the activation energy bump going higher then falling to the product level.

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17
Q

In an exothermic reaction, what will the reaction profile show?

A

The energy of the reactants will be higher than the energy of the products.

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18
Q

What is activation energy?

A

Minimum energy needed to start a reaction.

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19
Q

Define bond energy.

A

Energy needed to break one mol of a particular bond and is measures in kJ/mol.

20
Q

Formula for bond energy calculations.

A

Energy change = energy required to break bond (usually on the left of the equation) - energy required to make.

21
Q

What is a redox reaction in terms of oxygen?

A

A redox reaction is a reaction in which reduction and oxidation happens at the same time (of oxygen).

22
Q

What is reduction of oxygen?

A

Loss of oxygen from a substance.

23
Q

What is oxidation of oxygen?

A

Gain of oxygen by a substance.

24
Q

What is the reducing agent (in terms of oxygen)?

A

The reducing agent is the substance that reduces the substance with oxygen (coincidentally the substance that is oxidised).

25
What is the oxidising agent (in terms of oxygen)?
The oxidising agent is the substance that 'gives' its oxygen (oxidises) the other substance. (Coincidentally the reduced substance.)
26
What is oxidation and reduction in terms of electrons?
Oxidation is loss of electrons and reduction is gain of electrons.
27
What is an acid?
A substance that releases hydrogen ions when dissolved in water and a pH below 7.
28
What is a base and an alkali?
A base is a substance (metal oxide or hydroxide) that can neutralise acids. An alkali releases hydroxide ions when dissolved in water. A pH greater than 7.
29
What is the neutralisation reaction?
H+(aq) + OH-(aq) > H20 (l)
30
In neutralisation, acid +base > ?
acid + base > salt + water
31
Acid + Alkali > ?
acid + alkali > salt + water
32
Acid + Metal > ?
acid + metal > salt + hydrogen
33
Acid + Carbonate > ?
acid + carbonate > salt + water + carbon dioxide
34
What is the difference between a dilute and a concentrated acid?
- A dilute acid contains a low ratio of acid:volume solution. - A concentrated acid contains a high ratio of acid:volume solution.
35
What is a weak acid?
A weak acid is only partially ionised (dissociated). Only a small fraction of their H+ ions are released.
36
What is a strong acid?
A strong acid is fully ionised (dissociated). All of their molecules release H+ ions.
37
Describe the link between pH and hydrogen ion concentration,
if the concentration of hydrogen ions increases by a factor of 10, the pH of the solution decreases by 1 (more hydrogen ions, more acidic, lower pH), vice versa.
38
What is an electrolyte?
A compound in its liquid state or solution that has mobile ions which conduct electricity.
39
What is the negative electrode and the positive ions?
Negative electrode: Cathode | Positive ions: Cations
40
What is the positive electrode and the negative ions?
Positive electrode: Anode | Negative ions: Anions
41
In aqueous solutions, what are the general ions that will be present?
Hydrogen and hydroxide ions from water. (H+ + OH- > H20 ). The ions from the ionic compound.
42
At the cathode (electrolysis of aqueous solutions), in what situation will hydrogen gas be produced?
If hydrogen is more reactive than the metal, the metal will be produced. If hydrogen is less reactive than the metal, hydrogen gas will be produced.
43
At the anode (electrolysis of aqueous solutions), what happens if halide ions are present?
If halide ions are present, the halides will be formed, if not then oxygen will be formed.
44
What is the half equation for oxygen being formed at the anode?
4OH(-) > O2 + 2H20 + 4e(-)
45
What differs electroplating from standard electrolysis?
Electroplating uses non-inert electrodes that change during electrolysis.
46
What role do the cathode, anode and electrolyte play in electroplating?
The cathode is the object you want to coat, the anode is the coating material. The electrolyte is a solution containing ions of the coating metal.