C3.4 Flashcards
(22 cards)
Electrolyte
Solution that contains an ionic compound (where ions are free to move)
What would you do if u had an insoluble substance for electrolysis?
Melt it into molten liquid to allow ions to be free to move
Why are electrodes made of
They are solid conductors that are made from metal or carbon, or graphite
Which side is which for the electrodes?
Anode on the right, cathode on the left
Electrolysis
Splitting an ionic compound using electricity
Where are cations attracted to and what happens?
Positive anode, they get discharged to become a neutral atom.
Where are the anions attracted to and what happens?
The negative cathode, becomes discharged, forms layers of molten substance
What happens at anode?
Oxidation, loss of electrons
What happens at cathode?
Reduction, gain of electrons
Where do electrons flow?
Electrons from cation pass to anode and then transported along wire to cathode using power of battery, and then passing the electrons to the anion to make a neutral ion.
Why can some metals not be reduced?
Reducing metals to become a neutral atom only works if it’s less reactive than carbon. The more reactive metals need to do electrolysis
Disadvantages of electrolysis
Expensive and requires a lot more energy
How do you make solid metal aqueous for electrolysis?
Purify metal, melt it to make it molten. Dissolve in water
Equation : H2O (l) (two arrows) H+(aq) + OH- (aq)
At negative cathode what’s the rule for the element that discharges first?
The ion of the least reactive element will be discharged.
At the cathode, what’s happens is a very reactive metal is present and what is the equation?
H+ ions are discharged.
4H+ (aq) + 4e- -> 2H^2 + (g) (reduction)
At the cathode, what happened if a low reactive metal is present and what’s the equation?
Metal is discharged.
4H+ (aq) + 4e- -> 2H^2 + (g) (reduction)
At the positive anode, what’s the rule if halides are present?
Halide gets discharged.
At the positive anode, what’s the rule if a hailed isn’t present?
Hydroxide always gets discharged.
What’s the equation if hydroxide is discharged and what reaction is this?
4OH- (aq) -> 2H2O (l) + O2 (g) + 4e- (oxidation)
What’s the coating in electroplating?
Anode
What’s the object that’s being coated?
Cathode