C3.6 Flashcards
(31 cards)
Define solvent
A substance that dissolves other substances (called solutes)
Define solute
A substance which is dissolved in a solvent. The end result of this is a solution.
NB. The amount of solute that dissolves depends on the solvent’s temperature.
Define saturated solution
A solution which is in equilibrium with undissolved solute.
Define solubility
The extent to which a solute will dissolve in a solvent.
What is Ks?
Likelihood of a solute to dissolve. Large numbers more likely.
What is the Ks equation for AB?
Ks = [A+] [B-]
What do square brackets represent?
The concentration.
What can solubility constants be used for?
- Calculate c of one ion in eq with another
- Determine if a ppt will form when two solutions are mixed
- Calculate solubility of ionic compound
How do you calculate Ks for AB from solubility?
Ks = [A+] [B-]
As A=B
Ks = [A+] squared. (or [B-] squared)
How do you calculate Ks for A2B from solubility?
Ks = [A+] squared x [B-]
As 2:1 ration of A:B, multiply A by 2 before squaring.
How do you calculate Ks for AB2 from solubility?
Ks = [A+] x [B-] squared.
As 1:2 ratio of A:B, multiply B by 2 before squaring.
How do you calculate solubility for AB from Ks?
x = root of Ks
How do you calculate solubility for A2B or AB2 from Ks?
x = cube root (Ks/4)
What is ionic product?
The concentration of each ion in ppt multiplied together.
How do you know if a reaction will form a precipitate?
If Ionic product is larger that Ks, ppt will be formed.
What happens if equal volumes of two solutions are combined?
The concentration of each solution halves.
What is the common ion effect?
The drop in solubility of AB if A+ or B- ions are added from another source.
What happens if A+ or B- ions are added to an AB solution?
The equilibrium will shift to favor the ppt as higher conc. of ions.
What are acids and bases relative to protons?
An acid is a proton donor, a base is a proton acceptor.
Note: A does not match A (acid acceptor)
What do strong acids and strong bases do in water?
They completely dissociate in water, fully releasing all of their ions.
What do weaker acids and bases do in water?
They do not dissociate fully in water, and only partially ionize.
What is Ka?
The acid dissociation constant
How do you calculate Ka?
[products]/[reactants]
How do you calculate the final conc. of an acid in solution?
acid - [H3O+]