C5.1 Exothermic and endothermic reactions / C6.2 Rate of reaction Flashcards

(59 cards)

1
Q

How does increasing the concentration of a solution affect the rate of reaction?

A

It increases the rate of reaction by causing more frequent collisions between particles.

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2
Q

How does increasing the pressure of a gas affect the rate of reaction?

A

It increases the rate by pushing gas particles closer together, increasing collision frequency.

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3
Q

How does increasing the surface area of a solid affect the rate of reaction?

A

It increases the rate by exposing more particles to react, leading to more collisions.

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4
Q

How does increasing the temperature affect the rate of reaction?

A

It increases the rate by giving particles more energy to collide with enough force to react.

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5
Q

How does a catalyst affect the rate of reaction?

A

It increases the rate by lowering the activation energy needed for the reaction to occur.

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6
Q

What happens to a catalyst at the end of a reaction?

A

It remains unchanged and can be used again.

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7
Q

Name two practical methods to investigate the rate of a reaction.

A

1) Measuring change in mass. 2) Measuring the volume of gas produced.

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8
Q

What can you learn from a graph showing the rate of reaction?

A

You can interpret how fast a reaction occurs and how it changes over time.

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9
Q

Why does a higher concentration lead to more frequent collisions?

A

Because there are more particles in the same volume, increasing the chance of collision.

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10
Q

Why does increasing temperature increase both the frequency and energy of collisions?

A

Particles move faster and have more kinetic energy, making successful collisions more likely.

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11
Q

How does a catalyst lower the activation energy?

A

It provides an alternative reaction pathway with lower energy requirements.

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12
Q

What is the unit for rate of reaction when measuring gas?

A

cm³/s or cm³/min depending on the experiment.

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13
Q

What safety precaution should you take when a reaction produces gas?

A

Use a gas syringe or an inverted measuring cylinder to safely collect and measure the gas.

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14
Q

What would a steep slope on a rate-of-reaction graph indicate?

A

A fast reaction rate.

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15
Q

What does a flat line on a reaction graph indicate?

A

The reaction has finished – no further products are being formed.

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16
Q

Give one example of a fast reaction.

A

Combustion or an explosion.

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17
Q

Give one example of a slow reaction.

A

Rusting of iron.

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18
Q

What is meant by “successful collision”?

A

A collision where particles hit with enough energy to overcome the activation energy and react.

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19
Q

What is an exothermic reaction?

A

A reaction that transfers thermal energy to the surroundings, increasing the temperature.

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20
Q

What is an endothermic reaction?

A

A reaction that absorbs thermal energy from the surroundings, decreasing the temperature.

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21
Q

How does a reaction pathway diagram show an exothermic reaction?

A

The products are at a lower energy level than the reactants, with energy released.

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22
Q

How does a reaction pathway diagram show an endothermic reaction?

A

The products are at a higher energy level than the reactants, with energy absorbed.

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23
Q

What is meant by the term enthalpy change, ∆H?

A

It is the thermal energy change during a reaction; negative for exothermic and positive for endothermic reactions.

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24
Q

What is activation energy (Ea)?

A

The minimum energy that reacting particles must have to start a reaction.

25
What should be labeled on a reaction pathway diagram?
Reactants, products, overall energy change (∆H), and activation energy (Ea).
26
Is bond breaking exothermic or endothermic?
Bond breaking is endothermic (energy is absorbed).
27
Is bond making exothermic or endothermic?
Bond making is exothermic (energy is released).
28
Give an example of an exothermic reaction.
Combustion of fuels.
29
Give an example of an endothermic reaction.
Thermal decomposition of calcium carbonate.
30
What is the energy profile shape of an exothermic reaction?
Starts high (reactants), drops low (products), with a peak (activation energy).
31
What is the energy profile shape of an endothermic reaction?
Starts low (reactants), rises high (products), with a peak (activation energy).
32
How can you tell a reaction is exothermic in a temperature experiment?
The temperature of the surroundings increases.
33
How can you tell a reaction is endothermic in a temperature experiment?
The temperature of the surroundings decreases.
34
What does a negative ∆H value mean?
The reaction is exothermic (energy is released).
35
What does a positive ∆H value mean?
The reaction is endothermic (energy is absorbed).
36
What does a large activation energy mean for a reaction?
It is less likely to happen spontaneously and may need more heat or a catalyst.
37
Why is bond breaking endothermic?
It requires energy to overcome the forces holding atoms together.
38
Why is bond making exothermic?
Energy is released when new bonds form between atoms.
39
40
What is the formula for calculating the rate of reaction?
Rate = Amount of reactant used or product formed ÷ Time taken
41
What is the unit of rate if mass is measured in grams and time in seconds?
g/s
42
What is the unit of rate if volume is measured in cm³ and time in seconds?
cm³/s
43
How can you calculate rate from the gradient of a graph?
Gradient = Change in y (product/reactant) ÷ Change in x (time)
44
In a rate of reaction graph, what does a steeper gradient mean?
A faster reaction rate
45
In a rate of reaction graph, what does a horizontal line indicate?
The reaction has stopped
46
What is the balanced symbol equation for the reaction of magnesium with hydrochloric acid?
Mg + 2HCl → MgCl₂ + H₂
47
What is the word equation for the decomposition of hydrogen peroxide?
Hydrogen peroxide → Water + Oxygen
48
What is the balanced symbol equation for the decomposition of hydrogen peroxide?
2H₂O₂ → 2H₂O + O₂
49
What is the symbol equation for the combustion of methane?
CH₄ + 2O₂ → CO₂ + 2H₂O
50
How can you calculate energy change (ΔH) from bond energies?
ΔH = Total energy needed to break bonds – Total energy released when new bonds form
51
What does a negative ΔH value mean?
The reaction is exothermic
52
What does a positive ΔH value mean?
The reaction is endothermic
53
What is the unit of enthalpy change (ΔH)?
kJ/mol
54
What is the energy change when bond making occurs?
Energy is released (exothermic)
55
What is the energy change when bond breaking occurs?
Energy is absorbed (endothermic)
56
What does the equation Q = mcΔT calculate?
Thermal energy transferred
57
In the equation Q = mcΔT, what does each symbol represent?
Q = energy (J), m = mass (g), c = specific heat capacity (J/g°C), ΔT = temperature change (°C)
58
How do you find the overall energy change from experimental data?
Measure temperature change and use Q = mcΔT
59
What equation is used to calculate the average rate over a time interval?
Average rate = Total change in quantity ÷ Total time