C6.2 - Organic Chemistry Flashcards

(64 cards)

1
Q

Homologous series

A

group of chemicals that have similar chemical structures

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2
Q

Alkanes homologous series

A

Hydrocarbons

contain just carbon and hydrogen

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3
Q

First four alkanes

A

Methane CH4
Ethane C2H6
Propane C3H8
Butane C4H10

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4
Q

Why are alkanes saturated?

A

all the atoms have formed bonds with as many other atoms as they can

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5
Q

Alkanes general formula

A

Cn H2n+2

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6
Q

What happens to an alkane during a complete combustion reaction?

A

they burn in oxygen to form carbon dioxide and water

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7
Q

Incomplete combustion

A

happens in a limited supply of oxygen
carbon monoxide is produced
carbon in the form of soot can be given out

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8
Q

Alkenes homologous series

A

Hydrocarbons

with at least on carbon-carbon double bond

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9
Q

Why are alkenes unsaturated?

A

they can make more bonds

double bond can open up - allowing the two carbon atoms to bond with other atoms

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10
Q

First four alkenes

A

Ethene C2H4
Propene C3H6
Butene C4H8
Pentene C5H10

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11
Q

How can you test for an alkene?

A

when an alkene is added to bromine water, alkene will decolourise the bromine water
turning it from orange to colourless
this is because the double bond can open up and form bonds with bromine

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12
Q

Hydrogenation

A

a process where alkenes react with hydrogen

hydrogen reacts with double-bonded carbons and adds across the double bond

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13
Q

Alkene general formula

A

Cn H2n

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14
Q

Alcohol general formula

A

Cn H2n+1 OH

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15
Q

Alcohol functional group

A

-OH

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16
Q

First four alcohols

A

Methanol CH3OH
Ethanol C2H5OH
Propanol C3H7OH
Butanol C4H9OH

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17
Q

How are carboxylic acids formed?

A

Alcohol is oxidised

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18
Q

How do you oxidise alcohol?

A

use an oxidising agent such as potassium magnate (VII)

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19
Q

Carboxylic acid general formula

A

Cn-1 H2n-1 COOH

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20
Q

Carboxylic acid functional group

A

-COOH

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21
Q

First four carboxylic acids

A

Methanoic acid HCOOH
Ethanoic acid CH3COOH
Propanoic acid C2H5COOH
Butanoic acid C3H7COOH

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22
Q

When an alcohol reacts with potassium manganate what do you observe?

A

A colour change

purple to colourless

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23
Q

How are polymers made?

A

by joining up lots of small molecules called monomers

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24
Q

Describe monomers that make up addition polymers

A

have a double covalent bond

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25
Unsaturated compounds
molecules with at least one double covalent bond between carbon atoms
26
Saturated compounds
molecules with only single bonds between carbon atoms
27
Additon polymerisation
lots of unsaturated monomer molecules (alkenes) open up their double bonds and join together to form polymer chains
28
Polymer name
type of monomer its made from with 'poly' in front of t | propene becomes polypropene
29
Polymer general formula
``` put the formula of the monomer in brackets and put a n after it C2H6 becomes (C2H6)n ```
30
What is needed to make addition polymers?
add chemicals called initiator after adding initiator to alkene monomer you may have to hear reaction mixture because addition polymers often involve flammable chemicals - use water baths rather than bunsen burners
31
Condensation polymerisation
usually involves two different types of monomers the monomers react together and bonds form between them - making polymer chains each monomer has to contain at least two functional groups - one on each end of the molecule each functional group can react with the functional group of another monomer - creating long chains of alternating monomers for eat new bond that forms a small molecule (such as water) is lost
32
Examples of condensation polymers
Polyesters | Polyamides
33
How do polyesters form?
carboxylic acid monomers and alcohol monomers react together
34
How do polyamides form?
carboxylic acid and amine monomers react together
35
What is nylon 6-6?
condensation polymer
36
How is nylon 6-6 made?
mix 1,6-dianohexane in water in one beaker mix 1,6-hexanedioyl in an organic solvent in another beaker pour one solution on top of the other if solution is not mixed two distinct layers form nylon is formed where these two layers meet can extract this layer by slowly lifting it out the beaker with tweezers
37
Naturally occurring polymers
DNA Carbohydrates Starch Proteins
38
DNA
complex molecule than contains genetic information | contains two strands of nucleotide monomers that bond together in polymerisation reaction
39
Carbohydrates
molecules containing carbon, oxygen and hydrogen | used by living things to produce energy
40
Starch
large complex carbohydrates made up of smaller units of carbohydrates known as glucose joined together in a long chain
41
Proteins
amino acids form polymers called protein s via condensation polymerisation they are polyamides
42
Crude oil
mixture of lots of different hydrocarbons | mainly made up fractions of alkenes
43
What is crude oil used as?
raw materials to create petrochemicals such as petrol or natural gas provides energy - generating electricity, heating homes used in plastics
44
How are compounds in crude oil separated?
Fractional distillation
45
Explain how compounds in crude oil are separated by fractional distillation
oil is heated until most of it is gas gas enters a fractionating column liquid part (bitumen) is drained off at the bottom in the column there is a temperature gradient - hot at the bottom and gradually gets colder as you go up longer hydrocarbons have higher boiling points - condense and drain out near the bottom shorter hydrocarbons have lower boiling points - condense and drain out near the top where its cooler so crude oil mixture is separated out into different fractions
46
What is in each fraction of a fractionating column
contains a mixture of hydrocarbons mostly alkanes with similar boiling points
47
Length of hydrocarbons as you go up the fractionating column
gets shorter as you go up the column
48
What is separated at each fraction? (top to bottom)
``` LPG Petrol Naphtha Kerosene (Paraffin) Disel Oil Bitumen ```
49
What is fractional distillation of crude oil dependant on?
relies on the fact that the different hydrocarbons have different boiling points
50
Two important types of bond in crude oil
Strong covalent bond between atoms within each hydrocarbon molecule Intermolecular forces of attraction between different hydrocarbon molecules
51
Is crude oil renewable or non-renewable?
non-renewable
52
Alternative energy sources
wind power | nuclear power
53
Cracking
it turns long alkane molecules into smaller alkane and alkene molecules (which are more useful)
54
Explain the process of cracking
form of thermal decomposition vaporised hydrocarbons are passed over powdered catalyst at abut 400°C - 700°C and at 70atm aluminium oxide is a catalyst used long-chain molecules split apart on the surfaces of the catalyst
55
Why are longer molecules formed in fractional distillation cracked into smaller ones?
theres more demand for products for products like petrol and diesel than bitumen and lubricating oil cracking also produces many alkene molecules - can be used to make polymers (plastics)
56
Reaction. between hydrogen and oxygen is...
exothermic - releases energy
57
Fuel cell
electrical cell thats supplied with a fuel and oxygen | uses energy from the reaction between them to produce electrical energy efficiently
58
Chemical cells
produce a potential difference arose the cell until all the reactants have been used up
59
How do hydrogen-oxygen fuel cell work?
Combine hydrogen and oxygen to release heat energy and water means no pollutants are made
60
Explain in detail how hydrogen-oxygen fuel cells work
electrolyte is solution of potassium hydroxide electrodes are porous carbon with catalyst hydrogen goes into anode compartment oxygen goes into cathode compartment (in fuel cells - anode is negative electrode, cathode is positive electrode) at negative electrode hydrogen loses electrons to produce H+ions - this is oxidation the H+ ions in the electrolyte move to the positive electrode at positive electrode oxygen gains electrons from the electrode and reacts with H+ions to make water - this is reduction electrons flow through an external circuit from the anode to the cathode - this is the electrical current overall reaction is hydrogen + plus oxygen which gives water
61
How does a hydrogen-oxygen fuel cell involve a redox reaction?
reduction at the cathode oxidation at the anode so the whole thing is a redox reaction
62
Half equation at negative electrode for hydrogen-oxygen fuel cell
H2 -> 2H+ + 2e-
63
Equation at the positive electrode for hydrogen-fuel cell
O2 + 4e- + 2H2O -> 4H2O
64
Disadvantage of Fuel cells
expensive to adapt current technology to run off fuel cells | hydrogen as fuel is difficult and expensive to extract and store