C8 - Rates and Equilibrium Flashcards

1
Q

What is the rate?

A

Tells us how fast reactants turn into products.

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2
Q

What are the two equations for mean rate of reaction?

A

quantity of product formed/ time

quantity of reactant used up/ time

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3
Q

What is rate measured in?

A

g or cm^3/s

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4
Q

What are the 3 ways to measure rate?

A
  • measuring the decreasing mass of a reaction.

-measuring the decreasing light passing through a solution.

-measuring the increasing volume of gas being given off.
a) using a glass syringe
b) using a measuring cylinder and trough.

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5
Q
A
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6
Q

For reactions to take place reactants must collide with?

A

Correct orientation and enough energy

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7
Q

Rate of reaction ____ if the frequency of successful collision ____.

A

Increase

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8
Q

What are the 5 factors that affect the rate of reaction by increasing frequency of successful collision?

A

Temperature
Surface area
Use of catalyst
Concentration of solutions
Pressure of gases

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9
Q

Why does rate of reaction increase when temperature increases?

A

Because particles have more energy and more around faster therefore particles collide more often and with more energy which increases the frequency of successful collisions.

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10
Q

Why does rate of reaction increase when concentration increases?

A

Because there’s more particles in a volume and therefore particles are closer together which increases the frequency of successful collisions.

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11
Q

Why does rate of reaction increase when a catalyst is introduced?

A

Because catalysts prouve an alternative route for the reaction with a lower activation energy which increases the frequency of successful collisions.

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12
Q

Why does rate of reaction increase when surface area of particles increases?

A

Because increase surface area means more particles are exposed therefore in contact with each other which increases the frequency of successful collisions.

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13
Q

Give examples of controlled reactions.

A

Nuclear to avoid explosions.
Rusting to reduce reactions by catalysts.
Mixing stuff to reduce time by giving more energy.
Combustion.
Food going bad by adding preservatives and reduce temp.

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14
Q

What is a catalyst?

A

A substance which increases the rate of reaction without being used up in the reaction.

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15
Q

Catalysts provide an alternative reaction route with a _____ activation energy.

A

Lower

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16
Q

What are examples of reversible reactions?

A

Melting and freezing
Neutralisation

17
Q

What’s a word equation example of a reversible reaction?

A

Hydrated copper sulphate —-> anhydrous copper sulphate + water

18
Q

What’s dynamic equilibrium?

A

When the reactants are turning into products at the same rate as the products are turning back into reactants.

19
Q

What are the three affecting compositions of dynamic equilibrium?

A

Concentration, temperature and pressure

20
Q

Who is le chatelier?

A

A french chemist who observed equilibrium mixtures.

21
Q

What does yield mean?

A

Amount

22
Q

How does concentration alter conditions?

A

Increasing the concentration of the reactant will ‘push’ or move the equilibrium to the product side as it opposes this increase and vice versa.

23
Q

How does altering temperature affect conditions?

A

Increasing the temperature of the system will move the equilibrium in the endothermic reaction.

24
Q

How does altering pressure change conditions?

A

Increasing the pressure of a system moves the equilibrium to the side with the fewer moles of gas and vice versa.