c8 rates of reaction Flashcards

(35 cards)

1
Q

mean rate of reaction
(reactant)

A

quantity of reactant used/time taken

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2
Q

mean rate of reaction (product)

A

quantity of product formed/time taken

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3
Q

unit of rate of reaction

A

g/s or cm3/s

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4
Q

when plotting a graph for rate of reaction what goes in the x-axis?

A

time

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5
Q

when do you draw a tangent on a specific point and calculate the gradient of the tangent?

A

to measure the rate of reaction at a specific time

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6
Q

factors which affect the rates of chemical reactions include:

A

-the concentration of reactants in the solution
-the pressure of reacting gasses
-the surface area of solid reactants
-the temperature
-presence of a catalyst

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7
Q

as you increase the temperature

A

the rate of reaction increases but same amount of products produced at the end

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8
Q

what is concentration?
-increasing concentration increases rate

A

the number of particles dissolved in a given volume of solvent

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9
Q

what is pressure
increased pressure=increased number of particles

A

a measurement of the number of particles in a given volume of gas

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10
Q

is the surface area of a block or powder of that block greater?

A

powder surface area greater

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11
Q

highest rate of reaction means

A

steepest gradient

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12
Q

what does collision explain?

A

how various factors affect the rates of reactions

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13
Q

chemical reactions can only occur when

A

reacting particles collide with each other and with sufficient energy

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14
Q

what is the activation energy?

A

the minimum amount of energy that particles must have to react is called the activation energy

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15
Q

what does increasing the concentration of reactants in solution, the pressure of reacting gases and the surface area of solid reactants increase?

A

the frequency of collisions so increases the rate of reaction

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16
Q

increasing the temperature increases the frequence of collisions. What does this do?

A

this makes the collisions more energetic,and so increases the rate of reaction

17
Q

increasing temperature

A

particles have more kinetic energy
move faster
more collisions per second
collide with more energy

18
Q

larger surface area (lump cut up into smaller parts)

A

more particles exposed to other reactants more frequent collisions

19
Q

catalysts

A

reduce the amount of energy needed for particles to have a successful collision

20
Q

enzymes act as catalysts in?

A

biological systems

21
Q

what are reversible reactions?
example: A + B ⇌C + D

A

reactions where the products of the reaction can react to produce the original reactions

22
Q

the direction of reversible reactions can be changed by?

A

changing the conditions
For example: heat
ammonium chloride ⇌ ammonia + hydrogen chloride cool

23
Q

if a reversible reaction is exothermic in one direction, what is it in the opposite direction?

24
Q

in reversible reactions, one reaction is exothermic and the other is endothermic so the same amount of energy is transferred in each case.
give an example

A

endothermic
ammonium chloride ⇌ ammonia + hydrogen chloride exothermic

25
when a reversible reaction occurs in apparatus which prevents the escape of reactants and products, when is equilibrium reached?
when the forward and reverse reactions occur exactly at the same rate
26
dynamic equilibrium
in a reversible reaction,rate of the forward reaction is equal o the rate of the backward reaction ina closed system
27
three conditions affect the rate of reaction:
-temperature -pressure -concentration
28
what is le chatlier's principle?
When a reaction has reached dynamic equilibrium and a change occurs the position of equilibrium will move to counteract the change. This concept is known as Le Chatelier's principle.
29
required practical:the disappearing cross reaction sodium thiosulfate solution + hcl-->sulfur (solid). what does sulfur do to the solution?
sulfur makes the solution go cloudy (turbidity)
30
steps for disappearing cross reaction:
-use a measuring cylinder put 10cm3 of sodium thiosulfate in conical flask -place the conical flask onto a printed black cross -add 10cm3 of hydrochloric acid into the conical flask -swirl solution , start a stopwatch
31
after some time, what happens to the solution?
it turns cloudy, stop clock when cross no longer visible
32
repeat again using?
lower concentrations of sodium thiosulfate
33
repeat the whole experiment and ?
calculate the mean with no anomalies included
34
reproducibility
can be repeated with different people or equipment but still same result
35
what is the problem with this experiment?
different eyesights , people might see cross for longer however same size printed cross helps solve this