CAP 11 Flashcards

(41 cards)

1
Q

arrhenius acids

A

produce hydrogen ions (H+) when they dissolve in water

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2
Q

Naming acids

A
  • Hydrogen + Non metals= hydro+ -ic acid
    (ex. hydrochloric acid)
  • Hydrogen and polyatomic ions:
    ate becomes -ic acid (chlorate- chloric acid)
    ite becomes -ous acid (chlorite- chlorous acid)
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3
Q

HCl

A

Hydrochloric acid

strong

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4
Q

HBr

A

Hydrobromic acid

strong

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5
Q

HI

A

Hydroiodic acid

strong

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6
Q

HCN

A

Hydrocyanic acid

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7
Q

HNO3

A

Nitric acid

strong

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8
Q

HNO2

A

Nitrous acid

weak

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9
Q

H2SO4

A

Sulfuric acid

strong

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10
Q

H2SO3

A

Sulfurous acid

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11
Q

H2CO3

A

Carbonic acid

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12
Q

HC2H302

A

Acetic acid

weak

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13
Q

H3PO4

A

Phosphoric acid

weak

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14
Q

H3PO3

A

Phosphorous acid

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15
Q

HClO3

A

Chloric acid

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16
Q

HClO2

A

Chlorous acid

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17
Q

Arrhenius bases

A

Produce hydroxide ions (OH-) in water

18
Q

Naming bases

A
Arrhenius bases are named as hydroxides
ex.
- NaOH sodium hydroxide 
- KOH potassium hydroxide 
-Al(OH)3 aluminium hydroxide
19
Q

Why arrhenius’ theory is shacky

A
  1. cannot explain why substances lacking hydroxide ions are bases ( ex. NH3)
  2. does not take into account the role of solvent
  3. does not describe accurately the role of H+ ion state ( does not exist as such in water)
20
Q

Bronsted-Lowry acids and bases

A
  • an acid is a substance that donates H+

- a base is a substance that accepts H+

21
Q

Lewis’ acids and bases

A
  • Acids can accept an electron pair

- Lewis bases can donate an electron pair

22
Q

Conjugate acid-base pairs

A

In any acid-base reaction there are two conjugate acid-base pairs.
Each pair is related by the loss and gain of one H+

23
Q

Amphoteric substances

A

Substances that can act as both acid and bases

ex. water: donates H+ when it reacts with a stronger base, accepts H+ when it reacts with a stronger acid

24
Q

Strong and weak acids

A
  • Strong acids completely ionizes in aqueous solutions

- Weak acids dissociate only slightly in water to form a few ions in aqueous solution

25
Strong acids
HI ( hydroiodic
26
HClO4
Perchloric acid | Strong
27
HF
Hydrofluoric acid | weak
28
Diprotic acids
Some acids have 2 H+ that dissociate one at a time
28
Diprotic acids
Some acids have 2 H+ that dissociate one at a time
29
Strong bases
- Dissociate completely in water - Are formed from metals of groups 1A and 2A include: LiOH NaOH KOH Ba(OH)2 Sr(OH)2
30
Weak base
Poor acceptors of H+ Include: NH3 ( ammonia) NaOCl ( bleach)
31
Acid dissociation constant
Is used to quantitatively measure the strength of an acid. Small: the equilibrium lies to the left Large: the equilibrium lies to the right When an acid is strong, it's Ka is not reported as dissociation is considered complete
32
Base dissociation constant
The stronger the base, the larger the Kb Small: equilibrium to the left Large: equilibrium to the right
33
Water dissociation constant
``` Kw= (H3O+) (OH-) Kw= 1.0 x 10^-14 ```
34
The pH scale
``` Used to describe the acidity of solutions Has values that usually range from 0 to 14 Acidic < 7 Basic > 7 Neutral= 7 Is a logarithm of the H30+ pH= - log (H3O+) pH decreases as the H3O+ increases ```
35
Acids react with
- metals to produce salt and hydrogen gas | - bases to produce a salt and water
36
A salt
An ionic compound that does not have H+ as the cation or OH- as the anion
37
Neutralization reaction
An acid reacts with a base to produce salt and water | The salt formed is the anion from the acid and the cation from the base
38
Antiacids
Substances that: - are used to neutralize excess stomach acid - are made of aluminum hydroxide and magnesium hydroxide mixtures
39
Acid base titration
- Procedure used to determine the concentration of an acid or a base by neutralizing it with a buffer
40
Indicator
Ex. phenolphthalein | is added to identify the endpoint